Catalytic transfer hydrogenation (CTH) was concerned great attention because it does not need the use of high pressure H2. A series of Cu catalysts has been prepared for transfer hydrogenation of biomass derived furfural to furfuryl alcohol with formic acid. The prepared Cu based catalysts are thoroughly characterized by various technique such as XRD, TPR, TPD (NH3, CO2), TEM, FT‐IR, UV‐Vis, N2O pulse chemisorption and N2‐physorption method. For a comparison point of view, the activity tests of various copper based catalysts have also been carried out. Among all these, MgAl2O4 (MA) supported copper catalyst was found to be the best to give 90% selectivity of furfuryl alcohol from transfer hydrogenation of furfural. The excellent yield of furfuryl alcohol could be attributed to high density of surface active Cu species, proper surface acidic‐basic properties and metal support interaction. Moreover, Cu/MA catalyst was simply recovered and reused, which retained its original activity even after reaction without significant loss of original activity. Supporting its reusability and stability.
Activated red brick (ARB) clay material proved superb catalyst for selective conversion of 1,5-pentanediol (1,5-PDO) to tetrahydropyran (THP) and 1,6-hexanediol (1,6-HDO) to oxepane (OP)
via
dehydration under vapor phase conditions in a continuous flow reactor. As per scanning electron microscopy (SEM), SEM-EDX and X-ray fluorescence (XRF) techniques, ARB clay catalyst majorly possessed silica (quartz), and iron oxide (hematite) species, and synergistic texture contributed to the catalytic efficiency for prolonged time-on-stream (TOS). The combination of active Lewis and Bronsted acidic sites with weak to mild acidic nature in the ARB clay obviously facilitates the dehydration reaction with high selectivity, tetrahydropyran (82%) and oxepane (89%). ARB clay displayed superior catalytic properties in the dehydration of alcohols compared with activities of commercial silica and α-Fe
2
O
3
as catalysts. Commercial silica and α-Fe
2
O
3
catalysts possessing the Lewis acidic sites only did not facilitate synchronous dehydration mechanism.
Of the biomass valorization technologies, bioethanol production and its selective conversion to diethyl acetal is of utmost importance to meet the increasing demand for bio-fuel additives.
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