Considering the potential applications of all-polymer solar cells (all-PSCs) as wearable power generators, there is an urgent need to develop photoactive layers that possess intrinsic mechanical endurance, while maintaining a high power-conversion efficiency (PCE).Herein a strategy is demonstrated to simultaneously control the intercalation behavior and nanocrystallite size in the polymer-polymer blend by using a newly developed, high-viscosity polymeric additive, poly(dimethylsiloxane-co-methyl phenethylsiloxane) (PDPS), into the TQ-F:N2200 all-PSC matrix. A mechanically robust 10wt% PDPS blend film with a great toughness was obtained. Our results provide a feasible route for producing high-performance ductile all-PSCs, which can potentially be used to realize stretchable all-PSCs as a linchpin of next-generation electronics.

Pen drawing is a method that allows simple, inexpensive, and intuitive two-dimensional (2D) fabrication. To integrate such advantages of pen drawing in fabricating 3D objects, we developed a 3D fabrication technology that can directly transform pen-drawn 2D precursors into 3D geometries. 2D-to-3D transformation of pen drawings is facilitated by surface tension–driven capillary peeling and floating of dried ink film when the drawing is dipped into an aqueous monomer solution. Selective control of the floating and anchoring parts of a 2D precursor allowed the 2D drawing to transform into the designed 3D structure. The transformed 3D geometry can then be fixed by structural reinforcement using surface-initiated polymerization. By transforming simple pen-drawn 2D structures into complex 3D structures, our approach enables freestyle rapid prototyping via pen drawing, as well as mass production of 3D objects via roll-to-roll processing.

The cell envelopes of many Gram-positive bacteria contain wall teichoic acids (WTAs). Staphylococcus aureus WTAs are composed of ribitol phosphate (RboP) or glycerol phosphate (GroP) backbones substituted with D-alanine and N-acetyl-D-glucosamine (GlcNAc) or N-acetyl-D-galactosamine (GalNAc). Two WTA glycosyltransferases, TarM and TarS, are responsible for modifying the RboP WTA with ␣-GlcNAc and ␤-GlcNAc, respectively. We recently reported that purified human serum anti-WTA IgG specifically recognizes ␤-GlcNAc of the staphylococcal RboP WTA and then facilitates complement C3 deposition and opsonophagocytosis of S. aureus laboratory strains. This prompted us to examine whether anti-WTA IgG can induce C3 deposition on a diverse set of clinical S. aureus isolates. To this end, we compared anti-WTA IgG-mediated C3 deposition and opsonophagocytosis abilities using 13 different staphylococcal strains. Of note, the majority of S. aureus strains tested was recognized by anti-WTA IgG, resulting in C3 deposition and opsonophagocytosis. A minority of strains was not recognized by anti-WTA IgG, which correlated with either extensive capsule production or an alteration in the WTA glycosylation pattern. Our results demonstrate that the presence of WTAs with TarS-mediated glycosylation with ␤-GlcNAc in clinically isolated S. aureus strains is an important factor for induction of anti-WTA IgG-mediated C3 deposition and opsonophagocytosis.

The lack of highly impermeable and highly flexible encapsulation materials is slowing the development of flexible organic solar cells. Here, a transparent and lowtemperature synthetic alumina single layer is suggested as a highly impermeable and a highly flexible encapsulation material for organic solar cells. While the water vapor transmission rate (WVTR) is maintained up to 100,000 bending cycles for a 25 mm bending radius (corresponding to 8.1% of the elastic deformation limit), as measured by in situ tensile testing with free-standing 50 nm-thick alumina films, the WVTR degraded gradually depending on the bending radius and bending cycles for bending radii less than 25 mm. The degradation of the WVTR in cyclic deformation within the elastic deformation limit is investigated, and it is found to be due to the formation of pinholes by a bond-switching mechanism. Also, encapsulated organic solar cells with alumina films are found to maintain 80% of initial efficiency for 2 weeks even after cyclic bending with a 4 mm bending radius.

Considering the potential applications of all-polymer solar cells (all-PSCs) as wearable power generators,there is an urgent need to develop photoactive layers that possess intrinsic mechanical endurance,w hile maintaining ah igh power-conversion efficiency (PCE).Herein as trategy is demonstrated to simultaneously control the intercalation behavior and nanocrystallite sizeinthe polymer-polymer blend by using anewly developed, high-viscosity polymeric additive,poly(dimethylsiloxane-co-methyl phenethylsiloxane) (PDPS), into the TQ-F:N2200 all-PSC matrix. Am echanically robust 10wt% PDPS blend film with ag reat toughness was obtained. Our results provide af easible route for producing high-performance ductile all-PSCs,w hichc an potentially be used to realizes tretchablea ll-PSCs as al inchpin of next-generation electronics.