Abstract. Boreal peatlands are major catchment sources of dissolved organic carbon (DOC) and nutrients and thus strongly regulate the landscape carbon balance, aquatic food webs, and downstream water quality. Climate change is likely to influence catchment solute yield directly through climatic controls on run-off generation, but also indirectly through altered disturbance regimes. In this study we monitored water chemistry from early spring until fall at the outlets of a 321 km2 catchment that burned 3 years prior to the study and a 134 km2 undisturbed catchment. Both catchments were located in the discontinuous permafrost zone of boreal western Canada and had  ∼  60 % peatland cover. The two catchments had strong similarities in the timing of DOC and nutrient yields, but a few differences were consistent with anticipated effects of wildfire based on peatland porewater analysis. The 4-week spring period, particularly the rising limb of the spring freshet, was crucial for accurate characterization of the seasonal solute yield from both catchments. The spring period was responsible for  ∼  65 % of the seasonal DOC and nitrogen and for  ∼  85 % of the phosphorous yield. The rising limb of the spring freshet was associated with high phosphorous concentrations and DOC of distinctly high aromaticity and molecular weight. Shifts in stream DOC concentrations and aromaticity outside the early spring period were consistent with shifts in relative streamflow contribution from precipitation-like water in the spring to mineral soil groundwater in the summer, with consistent relative contributions from organic soil porewater. Radiocarbon content (14C) of DOC at the outlets was modern throughout May to September (fraction modern carbon, fM: 0.99–1.05) but likely reflected a mix of aged DOC, e.g. porewater DOC from permafrost (fM: 0.65–0.85) and non-permafrost peatlands (fM: 0.95–1.00), with modern bomb-influenced DOC, e.g. DOC leached from forest litter (fM: 1.05–1.10). The burned catchment had significantly increased total phosphorous (TP) yield and also had greater DOC yield during summer which was characterized by a greater contribution from aged DOC. Overall, however, our results suggest that DOC composition and yield from peatland-rich catchments in the discontinuous permafrost region likely is more sensitive to climate change through impacts on run-off generation rather than through altered fire regimes.

On May 18, 1980, after more than a month of earthquakes and eruptions, Mount St. Helens, in southwestern Washington, exploded in a volcanic eruption more violent than any in the conterminous .United States during the 20th century. A lateral blast of hot gas and rock particles devastated an area of about 150 square miles on the northern side of the mountain knocking down trees to a distance of 15 miles. Several minutes later, a giant ash cloud rose to about 60,000 feet. Winds then carried the ash cloud across the United States, with heavy fallout and deposition in eastern Washington and parts of Idaho and Montana. Earlier, smaller eruptions deposited ash in western Washington and parts of Oregon and Canada.The hydrologic effects of the May 18 eruption have been both widespread and intense. During the eruption, a massive debris avalanche moved down the north flank of the volcano depositing about 3 billion cubic yards of rock, ice, and other materials in the upper 17 miles of the North Folk Toutle River valley. The debris deposits are about 600 feet thick in the upper reaches of the valley. Following the avalanche, runoff from the melted glaciers and snow, and possible outflow from Spirit Lake, caused an extraordinary mudflow in the North Fork Toutle River. The mudflow shattered and uprooted thousands of trees, destroyed most of the local bridges, and deposited an estimated 25,000 acre-feet of sediment in the Cowlitz River channel. A considerable amount of additional sediment was conveyed through the lower Cowlitz into the Columbia River where it was deposited and formed a shoal that blocked the shipping channel. Mudflows also occurred in the South Fork Toutle River and in tributaries on the east flank of Mount St. Helens which enter Swift Reservoir.As part of a concerted Geological Survey effort to study the volcanic event and to identify potential hazards, Survey hydrologists have mounted an intensive program to document the hydrologic effects of the eruptions. The major initial hydrologic findings are reported in this circular series. Quick, useful assessment was made possible only because the Survey has long conducted extensive water-resources investigations in the affected areas of Washington, Oregon, and Idaho. Hence, there was a well-defined basis for identification and documentation of the types and magnitudes of hydrologic changes.The Geological Survey Circular 850, "Hydrologic Effects of the Eruptions of Mount St. Helens, Washington, 1980," consists of individually published short chapters that emphasize data collection activities, field observations, and initial comparisons of preand post-eruption conditions. The series will cover hydrologic events occurring on May 18 in the Toutle and Cowlitz River; physical alteration of the Toutle River system; the chemical and physical quality of precipitation, streams, and lakes affected by volcanic ash fall; ash-leaching studies; and Mount St. Helens glaciers.

Despite occupying a small fraction of the landscape, fluvial networks are disproportionately large emitters of CO2 and CH4, with the potential to offset terrestrial carbon sinks. Yet the extent of this offset remains uncertain, because current estimates of fluvial emissions often do not integrate beyond individual river reaches and over the entire fluvial network in complex landscapes. Here we studied broad patterns of concentrations and isotopic signatures of CO2 and CH4 in 50 streams in the western boreal biome of Canada, across an area of 250,000 km2. Our study watersheds differ starkly in their geology (sedimentary and shield), permafrost extent (sporadic to extensive discontinuous) and land cover (large variability in lake and wetland extents). We also investigated the effect of wildfire, as half of our study streams drained watersheds affected by megafires that occurred 3 years prior. Similar to other boreal regions, we found that stream CO2 concentrations were primarily associated with greater terrestrial productivity and warmer climates, and decreased downstream within the fluvial network. No effects of recent wildfire, bedrock geology or land cover composition were found. The isotopic signatures suggested dominance of biogenic CO2 sources, despite dominant carbonate bedrock in parts of the study region. Fluvial CH4 concentrations had a high variability which could not be explained by any landscape factors. Estimated fluvial CO2 emissions were 0.63 (0.09–6.06, 95% CI) and 0.29 (0.17–0.44, 95% CI) g C m−2 year−1 at the landscape scale using a stream network modelling and a mass balance approach, respectively, a small but potentially important component of the landscape C balance. These fluvial CO2 emissions are lower than in other northern regions, likely due to a drier climate. Overall, our study suggests that fluvial CO2 emissions are unlikely to be sensitive to altered fire regimes, but that warming and permafrost thaw will increase emissions significantly.

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Abstract. Boreal peatlands are major catchment sources of dissolved organic carbon (DOC) and nutrients, and thus strongly regulate the landscape carbon balance, aquatic food webs, and downstream water quality. Climate change is likely to influence catchment solute yield directly through climatic controls on runoff generation, but also indirectly through altered disturbance regimes. In this study we monitored water chemistry from early spring until fall at the outlets of a 321 km2 catchment that burned 3 years prior to the study and a 134 km2 undisturbed catchment. Both catchments were located in the discontinuous permafrost zone of boreal western Canada and had ~60 % peatland cover. The two catchments had strong similarities in the timing of DOC and nutrient yields, but a few differences were consistent with anticipated effects of wildfire based on peatland porewater analysis. The four week spring period, particularly the rising limb of spring freshet, was crucial for accurate characterization of the seasonal solute yield from both catchments. The spring period was responsible for ~65 % of the seasonal DOC and nitrogen, and ~85 % of the phosphorous yield. The rising limb of spring freshet was associated with high phosphorous concentrations and DOC of distinctly high aromaticity and molecular weight. Shifts in stream DOC concentrations and aromaticity outside the early spring period were consistent with shifts in relative stream-flow contribution from precipitation-like water in the spring, to mineral soil groundwater in the summer, with consistent relative contributions from organic soil porewater. Radiocarbon content (14C) of DOC at the outlets was modern throughout May to September (fM: 0.99–1.05), but likely reflected a mix of aged DOC, e.g. porewater DOC from permafrost (fM: 0.65–0.85) and non-permafrost peatlands (fM: 0.95–1.00), with modern bomb-influenced DOC, e.g. DOC leached from forest litter (fM: 1.05–1.10). The burned catchment had significantly increased total phosphorous yield, and also had greater DOC yield during summer which was characterized by a greater contribution from aged DOC. Overall, however, our results suggest that DOC composition and yield from peatland-rich catchments in the discontinuous permafrost region likely is more sensitive to climate change through impacts on runoff generation rather than through altered fire regimes.