We report the synthesis of α-Fe1.4Ga0.6O3 compound and present its structural phase stability and interesting magnetic, dielectric and photo-absorption properties. In our work Ga doped α-Fe2O3 samples are well stabilized in α phase (rhombohedral crystal structure with space group R3C). Properties of the present composition of Ga doped α-Fe2O3 system are remarkably advanced in comparison with recently most studied FeGaO3 composition. At room temperature the samples are typical soft ferromagnet, as well as direct band gap semiconductor. Dielectric study showed low dielectric loss in the samples with large enhancement of ac conductivity at higher frequencies. Optical absorption in the visible range has been enhanced by 4 to 5%. This composition has exhibited large scope of tailoring room temperature ferromagnetic moment and optical band gap by varying grain size and non-ambient (vacuum) heat treatment of the as prepared samples by mechanical alloying.
Summary
In the recent decade, lithium‐ion batteries have flourished in the mobile market to a greater extent. Despite its versatile commercial applications in various fields, it faces critical issues that restrict by safety concerns including leakage, combusting, or even explosions because of the low boiling point of liquid organic electrolytes. In order to mitigate these difficulties, solid electrolytes can be a potential choice. Polymer‐based solid Li‐ion batteries have been attracting researchers for accomplishing high performance. However, poor mechanical strength and low transport of Li+ ions inside the cell remain prominent challenges for its commercialization. To solve these issues and enhance the overall performance, polymer‐based nanocomposite electrolytes developed by incorporating the nanofillers into the polymer matrix have been investigated to a greater extent. This review briefly elaborates on the recent progress of polymer nanocomposite electrolytes for lithium‐ion batteries, factors affecting its performance, and various models used in the interpretation of its performance.
We have synthesized the composition of Fe 3(1-x) Co 3x O 4 (x =0.1, 0.3 and 0.5) spinel ferrite using the techniques of mechanical alloying, high temperature annealing of milled samples and conventional solid state sintering. We present here comparative results of the crystal structure formation and dielectric properties of the materials studied at room temperature. The crystalline structure of the single phased samples is cubic spinel phase with space group Fd3m. The alloying of two spinel oxides (i.e., Fe 3 O 4 and Fe 3 O 4) is also complemented from FTIR spectrum. Impedance spectroscopy suggested only one semi circle in the Cole-Cole plot of mechanical milled samples, which indicated the dominant grain boundary contribution in the conduction mechanism. In addition to the grain boundary contribution, the electrical conduction from grains is also substantial in the single phased compositions of the present material. The present results could be interesting in tailoring the electrical conductivity in magnetic nanocomposite.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.