Compounding natural additives with synthetic polymers allows developing more eco-friendly materials with enhanced biodegradability. The composite films based on low-density polyethylene (PE) with different content of natural rubber (NR) (10–30 wt%) were investigated. The influence of NR content on structural features, water absorption and mechanical properties of the composites were studied. The 70PE/30NR composite is characterized by the uniform distribution and the smallest size of NR domains (45 ± 5 μm). A tensile test was satisfied by the mechanical properties of the biocomposites, caused by elasticity of NR domains. The tensile strength of 70PE/30NR composite film is 5 ± 0.25 MPa. Higher water absorption of PE/NR composites (1.5–3.7 wt%) compared to neat PE facilitates penetrating vital activity products of microorganisms. Mycological test with mold fungi and full-scale soil test detected the composite with 30 wt% of NR as the most biodegradable (mass loss was 7.2 wt% for 90 days). According to infrared spectroscopy and differential scanning calorimetry analysis, NR consumption and PE structural changes in the biocomposites after exposure to soil occurred. The PE/NR composites with enhanced biodegradability as well as satisfied mechanical and technological properties have potential applications in packaging and agricultural films.
Recently, environmental problems caused by the overproduction and consumption of synthetic polymer materials led to an urgent need to develop efficient methods for processing plastics. The accumulation of polymer waste for their subsequent incineration does not solve the problem due to the limited areas of landfills for waste storage. In addition, the incineration of polymer waste can cause toxic air pollution, which, in turn, does not contribute to an improvement in the environmental situation. Recycling plastics, although a more environmentally friendly waste disposal method, requires significant labor and energy costs and can be performed a limited number of times. Thus, the most promising solution to this problem is the creation of biodegradable polymers capable of degradation with the formation of simpler chemical structures (water, carbon dioxide, biomass, etc.), which are easily included in the metabolic processes of natural biological systems. The article provides an overview of the main trends in the creation of biodegradable composites for the needs of agriculture. Also, the article proposes a new composition based on polyethylene with natural rubber that surpasses existing biodegradable materials in a number of physical and mechanical characteristics and has the ability to complete biodegradation in 60 months. It is shown that the studies carried out to date indicate that these composites are highly promising for the creation of biodegradable packaging materials with good performance characteristics. Thus, it was concluded that further research on composites based on polyethylene and natural rubber is important.
As part of the research, the authors proposed a recipe and production technology for a line of biodegradable materials based on low density polyethylene with different content of natural rubber. The advantages of using such materials include their high operational physical and mechanical properties, which make it possible to create a wide range of various products from these materials, as well as their high biodegradability in soil. So for the composition PE/NR‐50/50, the weight loss in the soil within 18 months was more than 40%. In addition, using the example of the composition PE/NR‐50/50, the authors carried out calculations of the efficiency of organizing the production of material according to the developed recipe, which showed a high investment attractiveness of the implementation of such a project.
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