From a geological perspective, hydrogen has been neglected. It is not as common as biogenic or thermogenic methane, which are ubiquitous in hydrocarbon basins, or carbon dioxide, which is common in geologically-active areas of the world. Nevertheless, small flows of hydrogen naturally reach the Earth's surface, occur in some metal mines and emerge beneath the oceans in a number of places worldwide. These occurrences of hydrogen are associated with abiogenic and biogenic methane, Further research should aim to identify the extent of the hydrogen flux and its probable dominant role in the abiogenic production of hydrocarbons in Precambrian times, a natural process now largely replaced by biogenic participation. A similar industrial process replicates serpentinization, producing hydrogen and ultimately liquid hydrocarbons on a commercial scale in some countries. It remains to be proved whether a contribution from exploration can be made to any future Hydrogen Economy.

Organic-rich shale may contains significant amounts of gas held within fractures and micro-pores and adsorbed onto organic matter. In the US shale gas extracted from regionally extensive units such as the Barnett Shale currently accounts for ~6% of gas production. Shale gas prospectivity is controlled by the amount and type of organic matter held in the shale, thermal maturity, burial history, microporosity and fracture spacing and orientation.The main UK organic-rich shale sequences have been mapped at the surface and in the subsurface using a combination of outcrop, well and seismic data. Potential targets range in age from Cambrian to the late Jurassic: younger shales have been excluded because they have not reached the gas window, but they may possess a biogenic gas play. A GIS showing the distribution of potential reservoir units has been combined with information on hydrocarbon shows, thermal maturity, fracture orientation, gas composition and isotope data to identify potentially prospective areas for shale gas in the UK. These include Lower Palaeozoic shale basins on the Midland Microcraton, Mississippian shales in the Pennine Basin and Pennsylvanian shales in the Stainmore and Northumberland basin system.

The Variscides of southeast England are buried beneath post-Carboniferous cover. Interpretations of the basement are based mainly on deep boreholes. Geophysical signatures from the basement are contained within the regional gravity and magnetic data. A gravity stripping exercise has been undertaken to remove the gravitational effect of the post-Variscan cover to generate a residual gravity map. This map is interpreted along with integrated potential field modelling along four long interconnected profiles and compared with a revised pre-Permian subcrop map. The magnetic evidence suggests that Precambrian magnetic basement of the Midlands Microcraton has been buried southwards by north-vergent Variscan thusting over the foreland. North of the Variscan Front, shortwavelength anomalies superimposed upon this deep Precambrian source are due to shallower Silurian and Carboniferous volcanic rocks. Many residual gravity lows within the Rhenohercynian zone may be related to thick, low-density Devonian basins. In the English Channel a change in geophysical signature occurs north of the Portland-Wight Fault, coinciding with phyllites in the basement. Models are presented in which the English Channel magnetic anomalies originate within the pre-Permian basement. Comparisons with anomalies in the Southwestern Approaches suggest that the Portland-Wight Thrust is a terrane boundary, possibly a subduction-related suture, implying southerly directed Variscan subduction.

Seismic mapping of key Palaeozoic surfaces in the East Irish Sea-North Channel region has been incorporated into a review of hydrocarbon prospectivity. The major Carboniferous basinal and inversion elements are identified, allowing an assessment of the principal kitchens for hydrocarbon generation and possible migration paths. A major Carboniferous tilt-block is identified beneath the central part of the (Permian to Mesozoic) East Irish Sea Basin (EISB), bounded by carbonate platforms to south and north. The importance of the Bowland Shale Formation as the key source rock is reaffirmed, the Pennine Coal Measures having been eroded over wide areas as a result of Variscan inversion and erosion prior to Permian deposition. Peak generation from the Bowland source rock coincided with maximum burial of the system in late Jurassic/early Cretaceous time. A multiphase history of Variscan inversion has generated numerous structural traps whose potential remains essentially unexplored. Leakage of hydrocarbons from these into the overlying Triassic Ormskirk Sandstone reservoirs is likely to have occurred on a number of occasions, but currently unknown is how much resource remains in place below the Base-Permian unconformity. Poor permeability in the Pennsylvanian strata beneath the Triassic fields is a significant risk; the same may not be true in the less deeply buried marginal areas of the EISB, where additional potential plays are present in Mississippian carbonate platforms and latest Pennsylvanian clastic sedimentary rocks. Outside the EISB, the North Channel, Solway and Peel basins also contain Devonian and/or Carboniferous rocks. There have however been no discoveries, largely a consequence of the absence of a high quality source rock and a regional seal comparable to the Mercia Mudstone Group and Permian evaporites of the Cumbrian Coast Group in the EISB. The productive oil and gas fields of the EISB evidence a working, Carboniferous-sourced petroleum system. Whilst a great deal may be known of the Triassic reservoir and seal (Meadows et al. 1997), little is known about Carboniferous and Permian petroleum systems at depth and in adjacent basins, that may offer significant additional potential. Following the Wood Review (2014), Palaeozoic plays, including that of the greater Irish Sea area were identified as priority for building regional digital datasets and stimulating exploration. In response, the 21 st Century Exploration Roadmap: Palaeozoic Project running from 2014-2016 and openly released in 2017, undertook regional scale seismic and well interpretation, source and reservoir screening studies and basin modelling. This paper provides a re-interpretation of the structural history of the greater Irish Sea, and its influence on potential Carboniferous and Permian prospectivity including the marginal basins. The Carboniferous structure and stratigraphy of the UK sector of the East Irish Sea-North Channel region has been reviewed using all available well and seismic reflection data. The project interpreted about 40,0...