Oxygen and fluorine adsorption and their coadsorption on the (111) unreconstructed surface of semiconductors InAs and GaAs were studied using the projector augmented-wave method with the generalized gradient approximation for the exchange−correlation functional and hybrid functional approach. The energetically preferable adsorbate sites on the surface were determined. It is shown that fluorine adsorption above surface cations on the A III B V (111)A-(1 × 1) unreconstructed surface leads to a removal of the surface state formed by cation p z -orbitals and to an unpinning of the Fermi level, whereas oxygen adsorption induces additional surface states in the band gap. The influence of fluorine and oxygen coadsorption and also fluorine concentration on the surface states in the band gap is discussed. It is shown that oxygen-induced surface states are completely or partially removed from the band gap by fluorine coadsorption if it forms bonds with cation surface atoms involved in an interaction with oxygen. The increase of fluorine concentration leads to considerable changes of the near-surface-layer structure due to the penetration of both electronegative adsorbates into the substrate and affects the electron properties of oxygen/ A III B V (111) interface.
We developed and applied a method of InAs passivation in the low-energy plasma of Townsend discharge. The controlled interface oxidation in the Ar:O2:CF4 gas mixture under visualization of gas discharge plasma allowed growing thin homogeneous films in the range of 5–15 nm thickness. Oxidation with the addition of CF4 in gas-discharge plasma led to the formation of In and As oxyfluorides with a wide insulating gap and isostructural interface with unpinned Fermi level behavior. The metal-oxide-semiconductor structure showed excellent capacitance-voltage characteristics: small frequency dispersion (<15 mV), density of interface states (Dit) in the gap below 5 × 1010 eV–1cm−2, and fixed charge (Qfix) below 5 × 1011 cm−2.
Comparative
experimental and theoretical studies of the fluorine/oxygen
ratio influence on the structural and electronic properties of the
anodic layer (AL)/InAs interface by XPS, HRTEM, C–V (77K)
measurements and ab initio calculation of fluorine and oxygen adsorption
on the InAs(111)A-(1 × 1) unreconstructed surface were performed.
The well-ordered transition layer (TL), composed of indium and arsenic
oxyfluorides, and extension of the interplanar distance at the fluorinated
anodic layer (FAL)/InAs interface were experimentally revealed. The
theoretical modeling of AL/InAs and FAL/InAs interfaces showed that
the fluorinated TR formation removes the InAs surface distortion,
whereas the In(InAs)–F–As(FAL) and In(InAs)–O–As(FAL)
bond formation is a reason for the interplanar distance increase between
FAL and the InAs surface. The decrease of the interface state density
in the InAs bandgap and the Fermi level unpinning at the FAL/InAs
interface result from the positive charge increase on FAL arsenic
atoms near the InAs surface during the As–F bonds formation,
while the electron accumulation on oxygen atoms and InAs subsurface
arsenic atoms is the reason for the states appearance in the InAs
bandgap at the anodic (native) oxide/InAs interface.
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