We use self-consistent mean field methods and analytical theory to determine the behavior of AB copolymers at the interface between two incompatible homopolymers, A and B. We calculate the reduction in interfacial tension, γ, resulting from the copolymers localizing at the A/B interface. We examine the effects of chain length, composition, and molecular architecture on the efficiency of the copolymers. In particular, we compare the interfacial behavior of different linear copolymers (random, alternating, and diblock) and various branched copolymers (stars and combs). At fixed molecular weight, the diblock copolymers are the most efficient at reducing γ. However, when we compare random and comb copolymers with diblocks at different molecular weights, we observe that the longer random or comb copolymers are more efficient than short diblocks. These studies allow us to predict the reduction in interfacial tension produced by a wide variety of copolymers and, thereby, permit a rational design of cost-effective and efficient compatibilizers.

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Cardiac function and oxygen consumption were measured in 25 patients who underwent amputation for peripheral vascular disease (PVD), and in five similarly aged control patients with PVD. Five patients at each of the midfoot, Syme's, below-, through-, and above-knee amputation levels and the five controls were measured at rest, normal walking speed, and maximum walking speed on a treadmill. At normal walking speed, all of the patients functioned at approximately 80% of their cardiac capacity. Normal walking speed and cadence decreased and oxygen consumption per meter walked increased with more proximal amputation. The ratio of cardiac function and oxygen consumption at normal walking speed as compared with at rest increased with more proximal amputation, and the capacity to increase walking speed and oxygen consumption lessened. Our results suggest that peripheral vascular insufficiency amputees function at a level approaching their maximum functional capacity. At more proximal amputation levels, the capacity to walk short or long distances is greatly impaired.

[1] On 29 April 1998, a coronal mass ejection (CME) was emitted from the Sun that had a significant impact at Earth. The terrestrial magnetosphere became more electrically active during the storm passage. Less explored is the effect of such a storm on an exposed rocky body like our Moon. The solar-storm/lunar atmosphere modeling effort (SSLAM) brings together surface interactions, exosphere, plasma, and surface charging models all run with a common driver -the solar storm and CME passage occurring from 1 to 4 May 1998. We present herein an expanded discussion on the solar driver during the 1-4 May 1998 period that included the passage of an intense coronal mass ejection (CME) that had >10 times the solar wind density and had a compositional component of He ++ that exceeded 20%. During this time, the plasma mass flux to the exposed lunar surface increased by over 20 times compared to the nominal solar wind, to a value near 10 À13 kg/m 2 -s. Over a two day CME passage by the Moon, this amount approaches 300 tons of added mass to the Moon in the form of individual proton and helium ions. Such an increase in ion flux should have a profound impact on sputtering loss rates from the surface, since this process scales as the mass, energy, and charge state of the incident ion. Associated loss processes were addressed by SSLAM and will be discussed herein.

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