Some members of the vegetal kingdom can achieve surprisingly fast movements making use of a clever combination of evaporation, elasticity and cavitation. In this process, enthalpic energy is transformed into elastic energy and suddenly released in a cavitation event which produces kinetic energy. Here we study this uncommon energy transformation by a model system: a droplet in an elastic medium shrinks slowly by diffusion and eventually transforms into a bubble by a rapid cavitation event. The experiments reveal the cavity dynamics over the extremely disparate timescales of the process, spanning 9 orders of magnitude. We model the initial shrinkage as a classical diffusive process, while the sudden bubble growth and oscillations are described using an inertial-(visco)elastic model, in excellent agreement with the experiments. Such a model system could serve as a new paradigm for motile synthetic materials.
When two sessile drops of the same liquid touch, they merge into one drop, driven by capillarity. However, the coalescence can be delayed, or even completely stalled for a substantial period of time, when the two drops have different surface tensions, despite being perfectly miscible. A temporary state of non-coalescence arises, during which the drops move on their substrate, only connected by a thin neck between them. Existing literature covers pure liquids and mixtures with low surface activities. In this paper, we focus on the case of large surface activities, using aqueous surfactant solutions with varying concentrations. It is shown that the coalescence behavior can be classified into three regimes that occur for different surface tensions and contact angles of the droplets at initial contact. However, not all phenomenology can be predicted from surface tension contrast or contact angles alone, but strongly depends on the surfactant concentrations as well. This reveals that the merging process is not solely governed by hydrodynamics and geometry, but also depends on the molecular physics of surface adsorption.
Ring-shaped deposits can be often found after a droplet evaporates on a substrate. If the fluid in the droplet is a pure liquid and its contact line remains pinned during the process, then the mechanism behind such ring-shaped deposition is the well-known coffee-stain effect. However, adding small amounts of salt to such a droplet can change the internal flow dramatically and consequently change the deposition mechanism. Due to an increase of surface tension in the contact line region, a Marangoni flow arises which is directed from the apex of the droplet toward the contact line. As a result, particles arrive at the contact line following the liquid-air interface of the droplet. Interestingly, the deposit is also ring shaped, as in the classical coffee-stain effect, but with a radically different morphology: Particles form a monolayer along the liquid-air interface of the droplet, instead of a compact three-dimensional deposit. Using confocal microscopy, we study particle-perparticle how the assembly of the colloidal monolayer occurs during the evaporation of droplets for different initial concentration of sodium chloride and initial particle dilution. Our results are compared with classical diffusion-limited deposition models and open up an interesting scenario of deposits via interfacial particle assembly, which can easily yield homogeneous depositions by manipulating the initial salt and particle concentration in the droplet.
Liquid foams are excellent systems to mitigate pressure waves such as acoustic or blast waves. The understanding of the underlying dissipation mechanisms however still remains an active matter of debate. In this paper, we investigate the attenuation of a weak blast wave by a liquid foam. The wave is produced with a shock tube and impacts a foam, with a cylindrical geometry. We measure the wave attenuation and velocity in the foam as a function of bubble size, liquid fraction, and the nature of the gas. We show that the attenuation depends on the nature of the gas and we experimentally evidence a maximum of dissipation for a given bubble size. All features are qualitatively captured by a model based on thermal dissipation in the gas.
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