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19Increasing biofuel production on agricultural lands in tropical island nations will likely result 20 in increased deforestation [1], and also inflate food prices, especially in net food importing

This is a preprint of an article published in Biofuels, Bioproducts and Biorefining Borines, M.G., McHenry, M.P. and de Leon, R.L. (2011)Integrated

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Rice is a staple food crop, and its production generates large volumes of agricultural waste, rice straw. Several studies have proven that open-field burning and soil incorporation are unsustainable practices of managing rice straw, but remain as prevalent methods of treating and disposing of rice straw. An alternative solution is to harness the energy from rice straw via a small-scale heat conversion system for paddy drying applications, which can reduce rice grain post-processing costs and improve paddy storage conditions. This study investigated the energy flow, Greenhouse Gas (GHG) emissions, and cost of a small-scale rice-straw-based heat generation (RBHG) system using a downdraft furnace and a dryer simulator setup. The highest input energy and GHG emissions of 92% and 68%, respectively, were from the heat generation stage. The RBHG energy ratio was between 1.4 and 1.7, and the percent net energy was between 39 and 67%. The best case of RBHG offers a possibility of a net GHG avoided (−61 kg CO2-eq Mg−1), while the worst case (856 kg CO2-eq Mg−1) has a net GHG emission comparable with soil incorporation. The average total cost of RBHG is 0.096 USD kWh−1. Overall, RBHG technology has the potential to improve energy flow, GHG emissions, and the cost of rice production systems.

Faradaic electric double layer capacitor (EDLC) nanocomposites for desalination were synthesized using coconut-shell derived activated biochar (AB) and manganese dioxide (MnO2) for capacitive deionization (CDI). Three different co-precipitation methods were explored to produce the composite such as: (1) indirect liquid-phase combination (ILC) method; (2) direct liquid-phase combination (DLC) method; and (3) acid-assisted grafting oxidation combination (AGO) method. Surface characterization confirmed the presence of α-MnO2 incorporated on the mesoporous activated biochar surface (485.92 m2 g−1) for all the nanocomposites developed. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) tests show that the three methods yielded a quasi-rectangular and symmetric CV plot indicating good EDLC behavior and a steep EIS plot. The highest specific capacitance of 522.7 F g−1 at 5 mV s−1 was observed using AGO method. CDI tests under 1.2 V at varying NaCl concentrations show high capacitive performance of the synthesized electrodes. The ILC method nanocomposite exhibited superior electrosorptive performance with an electrosorption capacity of 114.11 mg g−1 at 500 ppm NaCl concentration. Due to the synergistic effects of the pseudocapacitive redox reaction of MnO2 and the outstanding double-layer charging of AB on the composite, it serves as a suitable CDI electrode for desalination.