> Fe > Co. As is seen in Figure 5, the metal atom displacements do follow this order. Moreover, the essentially constant Ct-N(NO) (1.93-1.98 Á) and particularly the N-N(NO) nonbonded distances (2.76-2.79 Á) provide confirmation that the nitrosyl nitrogen atom position (and by implication the metal atom position as well) is governed by minimizing the axial nonbonded interactions. We conclude that the minimum N-N nonbonded separation for an axial ligand in five-coordinate metalloporphyrins is -~2.80 Á; thus, structural adjustments must occur to prevent ••• separations significantly less than 2.80 Á.
Der Komplex (I) wird durch Reaktion von K‐tetrachloroplatinat(II) mit L‐2,3‐Diaminopropionsäure in verdünnter Salzsäure dargestellt und mit Chlor zu (II) oxidiert.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.