Polyaniline (PANI) was prepared by chemical oxidative polymerization of aniline monomers as emeraldine salt form. By the same method, polyaniline–cadmium sulfide nanocomposites were synthesized in the presence of different percentages (10–50 wt.%) of cadmium sulfide (CdS) which was prepared by using sol–gel method. The optical band gap was decrease with increasing of CdS concentration, that is obtained from UV-VIS measurements. From SEM and AFM, there is uniform distribution for cadmium sulfide nanoparticles in the PANI matrix. The electrical measurements of nanocomposites exhibit the effect of crystallite size and the high resistivity of CdS on the resistivity of nanocomposites. Emeraldine salt PANI, CdS and PANI–CdS nanocomposites were investigated as gas sensors. From this investigation, the sensitivity of PANI–CdS for NO2 gas increase with the increasing of operation temperature and the optimum sensitivity was obtained at 200[Formula: see text]C. The sensitivity of nanocomposites at best temperature (200[Formula: see text]C) was increased and faster response time with the increasing of CdS contents.
The nanocrystalline CdS powder was prepared using sol-gel method. The polyaniline were prepared using chemical oxidative polymerization of aniline. The PANI-CdS nanocomposites had been prepared via same method of polyaniline preparation and different concentrations of CdS (10, 20, 30, 40 and 50 wt%) were added. X-ray diffraction shows that the peaks of emeraldine salt polyaniline powder are located at 2θ = 21.
In this paper, two-phase colloidal method was employed to synthesis CuS nanoparticles with different Cu : S ratios. The characterization of prepared CuS involves structural, morphological and optical properties analysis. X-Ray Diffractometer indicate that the covellite CuS have hexagonal structure. Field Emission Scanning Electron Microscope showed the formation of spherical nanostructure of CuS. UV-Visible Spectrophotometer showed the two absorption peaks of CuS nanoparticles one at UV-Visible region and the second at near infra-red region and the energy gap increase with sulfur content.
In this paper, copper sulfide nanoparticles were synthesized by two-phase colloidal method with different reaction temperatures (140, 160, 180 and 200°C). The structural, morphological and optical properties of prepared CuS were analyzed by the X-Ray Diffractometer (XRD), Field Emission Scanning Electron Microscope (FESEM) and UV-VIS Spectrophotometer. The XRD peaks refer to the covellite copper sulfide with hexagonal structure. FESEM showed the rod formation at lower temperatures (140 and 160°C), whereas higher temperatures (180 and 200°C) form nanocrystals within spheres structures. UV-VIS showed that CuS nanoparticles have two absorption peaks, one at UV-VIS region and the second at NIR region and its energy gap decrease with increasing of reaction temperature.
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