Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) has become recognized as a sensitive, effi cient, and cost-effective approach to measuring the major-, minor-, and trace-solute compositions of individual fl uid inclusions in minerals. As a prerequisite for the routine analysis of natural inclusions in our laboratory, the precision and accuracy of the technique was assessed using sets of multi-element synthetic fl uid inclusions. Five multi-element standard solutions were prepared, and incorporated as fl uid inclusions in quartz crystals at 750 °C and 7 kbar. Fluid inclusions were ablated with a 193 nm ArF excimer laser and analyzed with a quadrupole ICP-MS, equipped with an octopole reaction cell for the removal of Ar-based interferences. The internal standard used in all cases was Na. Analytical precision for K, Rb, and Cs is typically better than 15% RSD, whereas Li, Mg, Ca, Sr, Ba, Mn, Fe, Cu, Zn, and Cl analyses are typically reproducible within 30% RSD. Measured concentrations approximate a Gaussian distribution, suggesting that analytical errors are random. Analyses for most elements are accurate within 15%. Limits of detection vary widely according to inclusion volume, but are 1 to 100 µg/g for most elements. These fi gures of merit are in excellent agreement with previous studies. We also demonstrate that, over the range investigated, precision and accuracy are insensitive to inclusion size and depth. Finally, the combination of our LA-ICP-MS analyses with microthermometric data shows that charge-balancing to NaCl-H 2 O equivalent chloride molality is the most valid approach to LA-ICP-MS data reduction, where chloride-dominated fl uid inclusions are concerned.

22This study comprises the first systematic classification of native gold geochemistry within 23 alkalic porphyry Cu-Au systems and the placer expression of such systems. The 24 geochemistry and mineral associations of gold from four alkalic porphyry deposits in British

Porphyry-epithermal and orogenic gold are two of the most important styles of gold-bearing mineralization within orogenic belts. Populations of detrital gold resulting from bulk erosion of such regions may exhibit a compositional continuum wherein Ag, Cu, and Hg in the gold alloy may vary across the full range exhibited by natural gold. This paper describes a new methodology whereby orogenic and porphyry-epithermal gold may be distinguished according to the mineralogy of microscopic inclusions observed within detrital gold particles. A total of 1459 gold grains from hypogene, eluvial, and placer environments around calcalkaline porphyry deposits in Yukon (Nucleus-Revenue, Casino, Sonora Gulch, and Cyprus-Klaza) have been characterized in terms of their alloy compositions (Au, Ag, Cu, and Hg) and their inclusion mineralogy. Despite differences in the evolution of the different magmatic hydrothermal systems, the gold exhibits a clear Bi-Pb-Te-S mineralogy in the inclusion suite, a signature which is either extremely weak or (most commonly) absent in both Yukon orogenic gold and gold from orogenic settings worldwide. Generic systematic compositional changes in ore mineralogy previously identified across the porphyry-epithermal transition have been identified in the corresponding inclusion suites observed in samples from Yukon. However, the Bi-Te association repeatedly observed in gold from the porphyry mineralization persists into the epithermal environment. Ranges of P-T-X conditions are replicated in the geological environments which define generic styles of mineralization. These parameters influence both gold alloy composition and ore mineralogy, of which inclusion suites are a manifestation. Consequently, we propose that this methodology approach can underpin a widely applicable indicator methodology based on detrital gold.

Crustal growth at convergent margins is generally thought to occur through accretion of juvenile arc crust and/ or addition of magmatic material to the edge of a craton (e.g., Rudnick, 1995). Arc-continent collision zones are thus major sites for crustal growth through time (e.g., Brown et al., 2011). Arc accretion generally leads to development of an accretionary orogen, associated magmatism and basin(s) (e.g., Cawood et al., 2009;Draut & Clift, 2012). The evolution of arc-continent collision zones is generally complex and shows a wide-range of variations depending on configuration of continental and arc crusts, and angle and rates of convergence (Brown et al., 2011). There is no simple model that explains the variations observed in modern and ancient arc-continent collisions.In western North America, the development of the northern Cordilleran accretionary orogen began with collision of early Mesozoic peri-Laurentian arcs with the continental margin in latest Triassic to

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Aeromagnetic lineaments interpreted from reduced-to-pole (RTP) magnetic grids were compared with gravity, topography, and field-based geologic maps to infer regional structural controls on hydrothermal mineral occurrences in a poorly exposed portion of the North American Cordillera in western Yukon and eastern Alaska. High-frequency and variable-intensity aeromagnetic lineaments corresponding to discontinuities with an aeromagnetic domain change were interpreted as steep-dipping and either magnetite-destructive or magnetite-additive faults. These structures were interpreted to be predominantly Cretaceous in age and to have formed after the collision of the Intermontane terranes with the ancient Pacific margin of North America. To demonstrate the reliability of the aeromagnetic interpretation, we developed a multidata set stacking methodology that assigns numeric values to individual lineaments depending on whether they can be traced in residuals and first vertical derivative of RTP aeromagnetic grids, isostatic residual gravity grids, digital topography, and regional geologic maps. The sum of all numeric values was used to estimate the likelihood of the aeromagnetic lineament as a true geologic fault. Fault systems were interpreted from zones of lineaments with high spatial density. Using this procedure, 10 major northwest-trending fault systems were recognized. These were oriented subparallel to the regional Cordilleran deformation fabric, the mid-Cretaceous Dawson Range magmatic arc, and well-established crustal-scale dextral strike-slip fault systems in the area. These orogen-parallel fault systems were interpreted to play a structural role in the emplacement of known porphyry Cu-Au and epithermal Au systems of mid-Cretaceous (115–98 Ma) and Late Cretaceous (79–72 Ma) age. The procedure also identified seven northeast-trending, orogen-perpendicular fault-fracture systems that are prominent in eastern Alaska and exhibit sinistral-to-oblique extensional kinematics. These structures were interpreted to govern the emplacement of Late Cretaceous (72–67 Ma) porphyry Mo- and Ag-rich polymetallic vein and carbonate replacement systems in the region.

Late Triassic to Early Jurassic porphyry Cu mineralization is common in British Columbia, yet there are few age-equivalent porphyry occurrences in Yukon. This study presents new data for the enigmatic Carmacks Copper Cu-Au-Ag deposit in south-central Yukon, Canada, which is hosted in amphibolite facies metamorphic inliers within the Early Jurassic Granite Mountain batholith. Sulfide mineralization occurs mainly as net-textured bornite and chalcopyrite in leucosome, and as chalcopyrite ± pyrite blebs and disseminations in amphibolite and quartz-plagioclase-biotite schist. Several studies suggest that the Carmacks Copper deposit and the nearby Minto deposit are related to porphyry belts in British Columbia, but constraining the timing of alteration, mineralization, and metamorphism has been difficult. This study establishes a geologic and high-precision geochronologic framework for sulfide mineralization and its host rocks at the Carmacks Copper deposit, using Re-Os dating of molybdenite, and chemical abrasion-thermal ionization mass spectrometry (CA-TIMS) analysis of both whole zircon grains and laser-cut fragments of complexly zoned zircon grains. Our data indicate that the igneous protolith of the metamorphic inliers formed at 217.53 ± 0.16 Ma, followed by peak metamorphism at amphibolite facies at 205.82 ± 0.23 Ma, which occurred prior to Granite Mountain batholith emplacement but subsequent to Cu-Au-Ag mineralization of the protolith. An early phase of the Granite Mountain batholith was emplaced at 199.84 ± 0.14 Ma, followed by the main phase at 195 to 194 Ma. A second generation of metamorphic zircon in migmatite at 196.01 ± 0.12 Ma represents a partial melting event associated with Granite Mountain batholith emplacement. Two petrographically distinct populations of molybdenite are present in unstrained, net-textured copper sulfides. A sample dominated by strained molybdenite yielded an 187Re/187Os age of 212.5 ± 1.0 Ma, which represents the minimum mineralization age of the protolith. A sample dominated by euhedral grains yielded an 187Re/187Os age of 198.5 ± 0.9 Ma, constraining the maximum age of sulfide remobilization. These results indicate that primary mineralization is >212.5 Ma and potentially coeval with the ~217.5 Ma generation of Late Triassic magmatism. The mineralized protolith, best interpreted as the potassic alteration zone of a Late Triassic (~217–213 Ma) porphyry Cu-Au system, was metamorphosed to amphibolite facies at ~206 Ma, and subsequently migmatized during 200 to 194 Ma intrusion of the Granite Mountain batholith. The chalcopyrite-bornite-dominant assemblage in neosome precipitated from an immiscible Cu-Fe-S melt phase that partly consumed xenocrystic molybdenite and reprecipitated new molybdenite grains. The Carmacks Copper deposit and the related Minto deposit are remnants of a Late Triassic porphyry belt, where a significant fraction of the original metal endowment was likely lost through digestion of mineralized rocks by midcrustal magma in the Early Jurassic. These Yukon deposits are rare examples of metamorphosed porphyry Cu systems in the global geologic record, where rapid tectonic burial following mineralization was the principal factor in their preservation.