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We present results for the isothermal adsorption kinetics of methane, hydrogen, and tetrafluoromethane on closed-ended single-walled carbon nanotubes. In these experiments, we monitor the pressure decrease as a function of time as equilibrium is approached, after a dose of gas is added to the cell containing the nanotubes. The measurements were performed at different fractional coverages limited to the first layer. The results indicate that, for a given coverage and temperature, the equilibration time is an increasing function of E/(k(B)T), where E is the binding energy of the adsorbate and k(B)T is the thermal energy. These findings are consistent with recent theoretical predictions and computer simulations results that we use to interpret the experimental measurements.

Mixtures of ethylene glycol and water are used in cooling the engines in automotive applications. Heat is transferred essentially under subcooled flow boiling conditions as the mixture flows over the hot surfaces, which are at temperatures well above the local saturation temperature of the mixture. Very little information is available in the literature on the subcooled flow boiling characteristics of this mixture. The present work focuses on obtaining experimental heat transfer data for water and its mixtures containing ethylene-glycol (0 to 40 percent mass fraction, limited by the maximum allowable temperature in the present setup) in the subcooled flow boiling region. The experimental setup is designed to obtain local heat transfer coefficients over a small circular aluminum heater surface, 9.5-mm in diameter, placed at the bottom 40-mm wide wall of a rectangular channel 3-mm×40-mm in cross-section. Available models for (a) subcooled flow boiling of pure liquids and (b) saturated flow boiling of binary mixtures are extended to model the subcooled flow boiling of binary mixtures.

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