High coercivity (9.47 kOe) has been obtained for oleic acid capped chemically synthesized CoFe(2)O(4) nanoparticles of crystallite size approximately 20 nm. X-ray diffraction analysis confirms the formation of spinel phase in these nanoparticles. Thermal annealing at various temperatures increases the particle size and ultimately shows bulk like properties at particle size approximately 56 nm. The nature of bonding of oleic acid with CoFe(2)O(4) nanoparticles and amount of oleic acid in the sample is determined by Fourier transform infrared spectroscopy and thermogrvimetric analysis, respectively. The Raman analysis suggests that the samples are under strain due to capping molecules. Cation distribution in the sample is studied using Mossbauer spectroscopy. Oleic acid concentration dependent studies show that the amount of capping molecules plays an important role in achieving such a high coercivity. On the basis of above observations, it has been proposed that very high coercivity (9.47 kOe) is the result of the magnetic anisotropy, strain, and disorder of the surface spins developed by covalently bonded oleic acid to the surface of CoFe(2)O(4) nanoparticles.
Efforts have been made to elucidate the origin of d(0) magnetism in ZnO nanocactuses (NCs) and nanowires (NWs) using X-ray-based microscopic and spectroscopic techniques. The photoluminescence and O K-edge and Zn L3,2-edge X-ray-excited optical luminescence spectra showed that ZnO NCs contain more defects than NWs do and that in ZnO NCs, more defects are present at the O sites than at the Zn sites. Specifically, the results of O K-edge scanning transmission X-ray microscopy (STXM) and the corresponding X-ray-absorption near-edge structure (XANES) spectroscopy demonstrated that the impurity (non-stoichiometric) region in ZnO NCs contains a greater defect population than the thick region. The intensity of O K-edge STXM-XANES in the impurity region is more predominant in ZnO NCs than in NWs. The increase in the unoccupied (occupied) density of states at/above (at/below) the conduction-band minimum (valence-band maximum) or the Fermi level is related to the population of defects at the O sites, as revealed by comparing the ZnO NCs to the NWs. The results of O K-edge and Zn L3,2-edge X-ray magnetic circular dichroism demonstrated that the origin of magnetization is attributable to the O 2p orbitals rather than the Zn d orbitals. Further, the local density approximation (LDA) + U verified that vacancies in the form of dangling or unpaired 2p states (due to Zn vacancies) induced a significant local spin moment in the nearest-neighboring O atoms to the defect center, which was determined from the uneven local spin density by analyzing the partial density of states of O 2p in ZnO.
We report template-free, microwave-irradiation-assisted growth of ZnS nanorods. Using this facile and high yield technique we could grow nanostructures of approximately 50-100 nm diameter and more than 1 µm in length. Effects of microwave power and irradiation time on the growth process were investigated. It was revealed that the time of refluxing plays a vital role in determining the thickness of the rods. This simple technique using a multimode microwave source may prove to be a potential tool for growing similar nanostructures of other oxide-, sulfide- and selenide-based compound semiconductors.
The correlation between sub-band gap absorption and the chemical states and
electronic and atomic structures of S-hyperdoped Si have been extensively studied,
using synchrotron-based x-ray photoelectron spectroscopy (XPS), x-ray absorption
near-edge spectroscopy (XANES), extended x-ray absorption fine structure (EXAFS),
valence-band photoemission spectroscopy (VB-PES) and first-principles calculation. S
2p XPS spectra reveal that the S-hyperdoped Si with the greatest
(~87%) sub-band gap absorption contains the highest concentration of
S2− (monosulfide) species. Annealing S-hyperdoped Si
reduces the sub-band gap absorptance and the concentration of
S2− species, but significantly increases the
concentration of larger S clusters [polysulfides
(Sn2−,
n > 2)]. The Si K-edge XANES spectra show that
S hyperdoping in Si increases (decreased) the occupied (unoccupied) electronic
density of states at/above the conduction-band-minimum. VB-PES spectra evidently
reveal that the S-dopants not only form an impurity band deep within the band gap,
giving rise to the sub-band gap absorption, but also cause the insulator-to-metal
transition in S-hyperdoped Si samples. Based on the experimental results and the
calculations by density functional theory, the chemical state of the S species and
the formation of the S-dopant states in the band gap of Si are critical in
determining the sub-band gap absorptance of hyperdoped Si samples.
The in-situ X-ray absorption spectroscopy of three tungsten oxide films was performed to study the electronic and atomic structures following repeated cycles of coloration and bleaching processes. The transparent tungsten oxide films become deep blue upon intercalation of Li + ions in the WO 6 octahedra when an external electrical bias was applied. These films reverted to transparent when a reverse external electrical bias was applied. W L 3 -edge X-ray absorption near-edge structure (XANES) measurements of the nanocrystalline and crystalline tungsten oxide films revealed that the intensity of the white-line feature decreases after coloration and recoverably increases after bleaching owing to the filling and unfilling of the W 5d-O 2p conduction band states. The second derivative of the W L 3 -edge XANES spectra indicated an increase in structural disordering following repeated cycles of coloration and bleaching. However, the extended X-ray absorption fine structure analysis showed that the nearestneighbor W-O bond distances in the samples overall remain unchanged by coloration and bleaching.The nanocrystalline tungsten oxide film exhibited more effective recovery ($97% after first cycle) of the electronic structures than the other two crystalline samples in terms of the filling and unfilling of the W 5d-O 2p conduction band states after repeated coloration and bleaching. These results show that the nanocrystalline tungsten oxide sample has superior electrochromic properties to the crystalline samples.
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