This study was conducted to assess the removal efficiency of fast green FCF (a dye) from aqueous medium using the photoFenton process. Fenton's reagent, a mixture of hydrogen peroxide (H 2 O 2 ) and ferric ions (Fe 3+ ), used to generate hydroxyl radicals ( OH), was used to attack the target contaminant and degrade it. A visible light source was used to provide the radiation needed in the photo-Fenton method (i.e. H 2 O 2 /Fe 3+ ). The effects of varying the parameters of ferric ion, fast green FCF and hydrogen peroxide concentrations, as well as pH, and light intensity on the reaction rate were determined. More effective and faster than Fenton's reagent in removing fast green FCF, the results show that the photo-Fenton method completely oxidizes and degrades fast green FCF into CO 2 and H 2 O. A tentative mechanism for photobleaching of the dye is proposed.
The photocatalytic degradation has been considered to be an efficient process for degradation of organic pollutants, which are present in the effluents released by industries. The photocatalytic bleaching was carried out on rhodamin-B (cationic dye) in the presence of iron (III) complex, hydrogen peroxide and was observed spectrophotometrically. The effect of various operating variables like pH, concentration of complex and dye, amount of H2O2 and light intensity etc. was also observed on the efficiency of the reaction. A tentative mechanism has also been proposed for this photocatalytic degradation of rhodamin-B. Keywords: Photocatalytic degradation, rhodamin-B, metal complexes, hydrogen peroxide
This study was conducted to assess the removal of the Naphthol Green B dye from aqueous medium using the photo-Fenton process. The Fenton reagent, a mixture of hydrogen peroxide and Fe3+ ions, was used to generate the hydroxyl radical (•OH) that degrades the dye. Experiments were conducted at laboratory temperature and atmospheric pressure to examine the effect of reaction conditions such as the concentration of Fe3+ ions, the dye and hydrogen peroxide, pH, and light intensity on the reaction rate. The progress of the photochemical degradation was monitored spectrophotometrically. The optimum photochemical degradation conditions were determined. Naphthol Green B was completely degraded into CO2 and H2O. A tentative mechanism for photochemical bleaching of the dye by the photo- Fenton reaction has been proposed.
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