We report on a polymer-waveguide-based temperature sensing system relying on switchable molecular complexes. The polymer waveguide cladding is fabricated using a maskless lithographic optical system and replicated onto polymer material (i.e., PMMA) using a hot embossing device. An iron-amino-triazole molecular complex material (i.e., [Fe(Htrz)2.85(NH2-trz)0.15](ClO4)2) is used to sense changes in ambient temperature. For this purpose, the core of the waveguide is filled with a mixture of core material (NOA68), and the molecular complex using doctor blading and UV curing is applied for solidification. The absorption spectrum of the molecular complex in the UV/VIS light range features two prominent absorption bands in the low-spin state. As temperature approaches room temperature, a spin-crossover transition occurs, and the molecular complex changes its color (i.e. spectral properties) from violet-pink to white. The measurement of the optical power transmitted through the waveguide as a function of temperature exhibits a memory effect with a hysteresis width of approx. 12 °C and sensitivity of 0.08 mW/°C. This enables optical rather than electronic temperature detection in environments where electromagnetic interference might influence the measurements.
For applications in optical communication, sensing or information projection in automotive lighting, polymer based optical devices are of keen interest. Optical structures such as waveguides and gratings are basic blocks for these devices. We report on a simple, versatile, and yet low-cost fabrication method suited for both binary and multilevel diffractive microstructures as well as multimode optical waveguides in polymers. The fabrication of the diffractive structures, i.e. gratings, with two and multiple levels, is achieved by using a maskless optical lithography system employing a spatial light modulator. With the same system, waveguide cladding structures are realized by stitching of multiple single exposure patterns. For replication of these structures on polymer, e.g. polymethyl methacrylate (PMMA), a lab-made hot embossing machine is used. We then employ UV curable material and doctor blading to realize the waveguide cores. The created diffractive and waveguide structures are characterized in terms of diffraction efficiency and optical propagation loss, respectively, showing good optical quality and performance. With our fabrication system we have demonstrated a diffraction efficiency of 71% for multilevel grating structure and a propagation loss for stitched waveguides of 2.07 dB/cm at a wavelength of 638 nm. These basic elements will be employed to realize entire optical measurement systems for applications in sensing and integrated photonics in the next step.
Highly-functional photonic sensor networks integrated in thin polymer foils offer great potential for versatile applications in the life sciences, medicine, environmental analytics or production technology. For their realization, suitable low-cost and high-throughput production techniques need to be developed. Here, we describe work towards this goal, i.e. the fabrication of multimode polymer waveguides through a combination of thermal imprint and doctor blading. For imprint master stamp fabrication, a combined Bosch and O2 plasma etching process in silicon is utilized. We also demonstrate stamp fabrication by an additive manufacturing method, i.e. by employing maskless UV lithography, to enhance the flexibility and cost-effectiveness of our approach. We, thus, realize various all-polymer waveguide arrays, beam splitters, and grating couplers which serve as basic elements to create more complex photonic circuits. We also demonstrate polymer based transmission lines comprising semiconductor as well as organic light sources and detectors. We discuss both the integration of semiconductor light sources and detectors such as verticalcavity surface-emitting lasers (VCSEL) and photo detectors as well as organic light emitting diodes (OLEDs) and organic photo detectors. In first applications, we combine these elements to create sensor arrays for measuring temperature, strain or refractive index. We show results of various sensor types utilizing different measurement principles implemented in laboratory environments so far. For example, a waveguide array containing a linear discontinuity which serves as elongation zone for displacement, strain or tilt measurement by detecting the intensity variation of the transmitted light propagating inside the structure is presented. In future, we plan to create more powerful sensor photonics networks for reliable and robust applications in real life, e.g. for point-of-care testing or production monitoring.
Information projection using laser-based illumination systems in the automotive area is of keen interest to enhance communication between road users. Numerous work on laser-based front end projection employing refractive and reflective optics has been reported so far, while for rear end illumination efforts are more scarce and a different optical design concept due to limited volumetric size and field of view regulations is required. Here, we report on a new and versatile approach for a laser-based rear end lighting system for automotive application which enables projection of information or signals to support other road users. The design is based on thin diffractive optical elements projecting the desired patterns upon illumination. Also, for protection of the road users from the steering laser beam, a diffusive back projection screen is designed to project information while fulfilling both the field of view and safety requirements. The projection system is based on a periodic diffusive structure made of an array of biconic lenses with sizes in the millimeter range. The field of view (FOV) from the simulated lens arrays complies with the angular requirements set by the Economic Commission for Europe (ECE). As a proof of concept, the diffusive screen is fabricated using microfabrication technology and characterized. In future, the screen will be combined with thin diffractive optical elements to realize an entire integrated projection system.
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