The incorporation of zinc hydroxy stannate (ZHS), calcium borates (CBs), and NP-100 as flame-retardant fillers in polypropylene (PP) ethylene propylene diene monomer (EPDM) blends was investigated. The composites were prepared using an internal mixer and were molded using a compression mold to form test samples. Studies on the effect of filler loading (15, 30, 45, and 60 vol%) on the flame-retardant, thermal stability, and tensile properties were reviewed. A study on flame retardancy and thermal stability of ZHS, CB, and NP-100 fillers found that NP-100 has better flame retardancy compared with ZHS and CB even though NP-100 exhibits lower thermal stability compared with ZHS and CB. The mechanical properties of ZHS are the highest, followed by CB. NP-100 has the lowest mechanical properties. Tensile strength, Young's modulus, and strain at break of 30 vol% ZHS are slightly higher compared with other loadings. In addition, 30 vol% CB has the highest mechanical properties for PP/EPDM/CB system but has slightly lower mechanical properties compared with 30 vol% ZHS-filled PP/EPDM composites.
Flame retardant fillers composed of zinc hydroxy stannate (ZHS), calcium borates (CaB), and NP-100 were embedded separately in 50% polypropylene (PP) and 50% ethylene propylene diene monomer (EPDM) blends. Several formulations containing flame retardant fillers, PP, and EPDM were prepared using an internal mixer and were molded in a compression mold to form test samples. The effects of filler loading (15, 30, 45, and 60 vol%) on the dielectric breakdown strength and contact angle were determined. It was found that PP/EPDM/NP-100 has higher breakdown strength than PP/EPDM/ZHS and PP/EPDM/CaB. The contact angle of PP/EPDM/NP-100 and PP/EPDM/ZHS showed an ascending order with filler loading, implying an increase in hydrophobicity. With regard to the PP/EPDM/CaB system, the contact angle showed an ascending order up to 30 vol% followed by a descending order at 45-60 vol%. Water absorption studies indicated that PP/EPDM/NP-100 has lower water absorption compared with PP/EPDM/ ZHS and PP/EPDM/CaB. PP/EPDM filled with 15 vol% NP-100 was found to exhibit interesting insulating properties in comparison with other composite systems, thanks to high breakdown voltage, good hydrophobicity, and low water absorption.
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