Salicylaldehyde, 2-hydroxyacetophenone, and 3,5-dichlorosalicylaldehyde react with 1,2-diaminoethane to give three symmetrical Schiff bases H 2 L 1 , H 2 L 2 , and H 2 L 3 , respectively. With Ru(III) ions, these ligands lead to three complexes: Ru(III)ClL 1 (1), Ru(III)ClL 2 (2), and Ru(III)ClL 3 (3). The purity of these compounds was estimated by TLC technique and microanalysis while their structures were supported by the usual spectroscopic methods such as NMR, infrared, and electronic spectra. The cyclic voltammetry in acetonitrile showed irreversible waves for all three ligands. Under the same experimental conditions, it was proved that the ruthenium is coordinated in the three complexes 1, 2, and 3 showing quasireversible redox systems. The behavior of these complexes and their comparison with cytochrome P450 are investigated using them as catalysts in the presence of molecular oxygen with an apical nitrogen base: 1-or 2-methylimidazole.
This work aimed to study anaerobic digestion of a new substrate made from the waste of Algerian date palm (Phoenix dactyliferaL.) in order to evaluate its biogas production capacity. The lignocellulosic component biodegradability and the process stability were also tested. Two reactors were launched with the same concentration of 20g total solid (TS)/L. A physical pre-treatment (grinding) of dried leaves lowered the substrate size below 2 mm. The theoretical methane yield (499 - 538 mL CH4/g of Volatile Solids (VS)) indicated a high substrate methanogen potential. The tested methane and biogas yield reached 130±6 mL CH4/gVS and 197±6 mL/g VS respectively. The biodegradability through the volatiles solid reduction was 29%. The total alkalinity (TA) value increased from the beginning to the end, due to the substrate nature which gave a high buffering capacity of the medium. During the stable process, a higher Chemical Oxygen Demand (COD) removal was reached with a value of 77.58%. The majority of the biogas yield was generated during the same period, which confirmed that the anaerobic digestion process stability is indispensable. Finally, this study was an opportunity to better exploit local by-products for the bioenergy production.
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