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Homogeneous charge compression ignition engines require a smart control system to regulate the input quantities of the engine in various operational conditions. Achieving an optimum combustion needs an appropriate system response for different engine loads and speeds according to the power acquired from the engine, as well as the amounts of emissions present in the exhaust. Therefore, performing a set of experimental tests together with numerical simulations in a wide range of conditions facilitates calibration of the input parameters of the engine. In this study, the effects of the thermodynamic parameters and the thermokinetic parameters on the engine output in the preliminary design stage were obtained at different speeds to determine the optimum exhaust emissions, the optimum combustion timing and the ranges of misfiring and knock, using multiple-zone thermodynamic modelling. On the assumption that the simulation cycle is closed, the probability density function was used to determine the initial conditions for the temperature and the residual gas from the previous cycle mass distribution in each area inside the cylinder. The results obtained proved that the kinetic properties of the mixture due to the effects of the the air-to-fuel ratio, the percentage of exhaust gas recirculation and the percentage of reformer gas have dominant effects on the output in comparison with the thermodynamic parameters such as the intake pressure and the intake temperature. At low speeds, exhaust gas recirculation retards combustion and delays engine knock. At higher engine speeds, the reformer gas advances combustion and improves misfiring.

Unfortunately, energy demands and destruction of the environment from uncontrolled manipulation of fossil fuels have increased. Climate change concerns have resulted in the rapid use of new, alternative combustion technologies. In this study, reactivity controlled compression ignition (RCCI) combustion, which can simply be exploited in internal combustion (IC) engines, is investigated. To introduce and identify extra insightful information, an exergy-based study was conducted to classify various irreversibility and loss sources. Multidimensional models were combined with the primary kinetics mechanism to investigate RCCI combustion, incorporating the second law of thermodynamics. The n-heptane, a highly reactive fuel, was supplied by direct injection into the cylinder, whereas premixed fuel was supplied through the intake port in an isooctane/n-heptane RCCI engine. For five n-heptane increments (5%, 7.5%, 15%, 25%, and 40%) and six different exhaust gas recirculation (EGR) rates (0%, 10%, 20%, 30%, 40%, and 50%), accumulation of different exergy terms was calculated. The results show that as EGR introduction increases from 0% to 50%, the exergy destruction increases from 21.1% to 28.9%. Furthermore, the value of exhaust thermomechanical exergy decreases from 18.4% to 14.4% of the mixture fuel chemical exergy. Among the five different high reactive fuel mass regimes, the 40% n-heptane mass fraction has the major heat transfer exergy owing to its advanced CA50 that exerts a unique influence on cylinder charge temperature of heat transfer layer. The utilization efficiency of exhaust in RCCI is less affected by the variation of reactive fuel mass fraction by contrast; it will significantly influence heat transfer availability. This study revealed that with increasing reactive fuel (n-heptane) from 7.5% to 40% the irreversibility decreased from 28.6% to 25.8% and the second law efficiency first increased from 43.2% to 44.6% at 15% n-heptane then decreased to 42.9% at 40% n-heptane.