The principal burning characteristics of a laminar flame comprise the fuel vapour pressure the laminar burning velocity, ignition delay times, Markstein numbers for strain rate and curvature, the stretch rates for the onset of flame instabilities and of flame extinction for different mixtures. With the exception of ignition delay times, measurements of these are reported and discussed for ethanol-air mixtures. The measurements were in a spherical explosion bomb, with central ignition, in the regime of a developed stable, flame between that of an under or over-driven ignition and that of an unstable flame. Pressures ranged from 0.1 to 1.4 MPa, temperatures from 300 to 393K, and equivalence ratios were between 0.7 and 1. 3
The paper reviews the practical problems in measuring a turbulent burning velocity that gives the mass rate of burning. These largely centre on identifying an appropriate flame surface to associate with the turbulent burning velocity, u t , and the density of the unburned mixture. Such a flame surface has been identified, in terms of the mean reaction progress variable,c, for explosive flame propagation in a fan-stirred bomb. Measurement ofc makes possible an estimation of the flame surface density, Σ, from the relationship Σ = kc (1 −c). It is shown that in such explosions, mass rates of burning derived from the measured total flame surface area agreed well with those found from the measured turbulent burning velocity. Flamelet considerations identify appropriate dimensionless correlating parameters for u t . As a result, correlations of turbulent burning velocity divided by the effective rms turbulent velocity, are plotted against the turbulent Karlovitz stretch factor, K, for different values of the Markstein number for flame strain rate, Ma sr . These plots cover a wide range of variables, including pressure and fuels, and are indicative of different regimes of turbulent combustion. At the lower values of K, there is some evidence of increases in u t and k due to high-frequency flame surface wrinkling arising from flame instabilities. These increase as Ma sr becomes more negative. It is found from the developed value of the mean flame surface density throughout the flame brush that, to a first approximation, an increase in u t for a given mixture is accompanied by a proportional increase in the volume of the brush. The analysis shows that the volume fraction of the turbulent flame brush that is reacting is quite small.
A novel double-slit curved wall-jet (DS-CWJ) burner was proposed and utilized for flame synthesis. This burner was comprised of double curved wall-jet nozzles with coaxial slits; the inner slit was for the delivery of titanium tetraisopropoxide (TTIP) precursor while the outer one was to supply premixed fuel/air mixture of ethylene (C 2 H 4 ) or propane (C 3 H 8 ). This configuration enabled rapid mixing between the precursor and reactants along the curved surface and inside the recirculation zone of the burner. Particle growth of titanium dioxide (TiO 2 ) nanoparticles and their phases was investigated with varying equivalence ratio and Reynolds number. Flow field and flame structure were measured using particle image velocimetry (PIV) and OH planar laserinduced fluorescence (PLIF) techniques, respectively. The nanoparticles were characterized using high-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), and nitrogen adsorption Brunauer-Emmett-Teller (BET) for surface area analysis. The flow field consisted of a wall-jet region leading to a recirculation zone, an interaction jet region, followed by a merged-jet region. The DS-CWJ burner revealed appreciable mixing characteristics between the precursor and combustion gases near the nozzle regions, with a slight increase in the axial velocity due to the precursor injection. The precursor supply had a negligible effect on the flame structure. The burner produced a reasonably uniform size (13-18 nm) nanoparticles with a high BET surface area (>100 m 2 /g). The phase of TiO 2 nanoparticles was mainly dependent on the equivalence ratio and fuel type, which impact flame height, heat release rate, and high temperature residence time of the precursor vapor. For ethylene flames, the anatase content increased with the equivalence ratio, whereas it decreased in the case of propane flames. The synthesized TiO 2 nanoparticles exhibited high crystallinity and the anatase phase was dominant at high equivalence ratios (ϕ > 1.6) for C 2 H 4 , and at low equivalence ratios (ϕ < 1.3) for the C 3 H 8 flame.
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