The irregular ionic lattice model (IILM) is applied to predict the vapor pressures and solubilities
of carbon dioxide dissolved in 1-n-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6])
and in 1-n-octyl-3-methylimidazolium tetrafluoroborate ([C8mim][BF4]) ionic liquids at temperatures ranging from 298.15 to 333.15 K. The model contains only two parameters; they are
shown to be independent of an arbitrarily chosen reference state. The parameters show a slight
dependence on temperature, but this dependence is ignored in computations to demonstrate
the rigor of the IILM in predicting CO2 solubility at high and low pressures at various
temperatures. Model predictions are compared against the experimental data of Anthony et al.
(J. Phys. Chem. B
2002, 106, 7315) and of Blanchard et al. (J. Phys. Chem. B
2001, 105, 2437).
The usefulness of the model is in predicting CO2 solubilities at temperatures and pressures
where experimental data are unavailable.
Note: Some activities fit into more than one category, so the total count exceeds the total number of identified deployment activities addressing buildings.
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