'IItc Sr(~12-Eu(212 and SrC'1,-EuCI, systems \yere investigated over the full composition rtiiigcs by the Guinicr polvder X-ray diffractioii techniqur. Ti1 the strontiuin chlorideciiropiiim dichloride system the solitbility from the both ends of reactants was found when fast cooling of t,hc mclt \ras uscd. In t.he strontium chloride-curopium trichloride system it solid solution for the composition rrgion up t o 20 mol per cent of EiiC1, and tn.0 new intermediate chlorides, Sr4EnC1,, and Sr,Eu,CI,,, were observed. The compounds crystallize in orthorhombic symmetry with lattice pararnehrs of 7.220( 2), 35.15(1), 6.790(4) and licxagorial 12.854(4) and 24.702(8), respectively.
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