Isopren (IV) kann in Gegenwart der Rhodium‐Komplexe (I), (II) oder (III) mit den Silanen (V) regio‐ und stereoselektiv zu den Z‐Butenen (VI) hydrosilyliert werden.
The catalytic hydrosilylation of the 1,4‐diaza‐1,3‐dienes (I) with the silane (II) in the presence of Rhodium(I) complexes carrying unsaturated diaza ligands produces the N‐silylated enediamine (III) and the tautomeric aminoimine (IV).
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