The improving effect of nanoparticles on wood dimensional stability is barely known nowadays. The expected result of the research was the improvement of the dimensional stability through bulk hydrophobization, as a result of impregnation with hydrophobic SiO 2 nanoparticles. Two different wood species, beech (Fagus sylvatica) and scots pine (Pinus sylvestris) were investigated. Two different treatments with silica nanoparticles were used. One treatment was a pure emulsion of modified (hydrophobized) silica nanoparticles (carrier material: ethanol), and another one was modified (hydrophobized) silica nanoparticles in tetrahydrofuran carrier material in combination with polydimethylsiloxane (PDMS) as a bonding agent. PDMS was used to improve the bonding of the silica nanoparticles to the wood structure. The impregnation with nanoparticles was successful. Shrinking and swelling properties decreased by 17-33%, depending on wood species and treatment. Water uptake and equilibrium moisture content decreased significantly as a result of the treatments (40-58%). Application of PDMS did not provide better dimensional stability compared to the treatment without it, however, it resulted in lower equilibrium moisture content and water uptake compared to the basic nano-SiO 2 treatment.

In this paper, a method for dimensional stabilization of wood through bulk hydrophobization was investigated using a sol–gel process resulting in in-situ formation of microporous SiO2 aerogel. Two different wood species, beech (Fagus sylvatica) and Scots pine (Pinus sylvestris) were investigated. The incorporation of microporous silica aerogel inside the cell wall and lumen was verified by scanning electron microscopy, energy dispersive spectrometry and Fourier-transform infrared spectroscopy. A leaching test using paper as model material proved the bonding of the aerogel to the cellulose component of the cell wall, which indicates a long-lasting effect of the treatment. The modification of wood with silica aerogel significantly improved its hygroscopicity and dimensional stability, decreased the equilibrium moisture content and water uptake beside a low weight percent gain. Permeability was reduced as a result of the silica aerogel deposition in the macro- and micropores of the modified wood. The treatment resulted in an obvious colour change as well.