This paper, the first in a series of four review papers, presents a brief summary of the fundamental properties and characteristics of ionic polymeric-metal composites (IPMCs) as biomimetic sensors, actuators and artificial muscles. The forthcoming three review papers, to follow this paper, will address in detail such fundamentals and, in particular, manufacturing techniques and the electronic and electromechanical characteristics of IPMCs (part II), the phenomenological modelling of the underlying sensing and actuation mechanisms in IPMCs (part III) and the potential application areas for IPMCs (part IV). This paper is a summary of all recent findings and current state-of-the art manufacturing techniques, phenomenological laws and mechanical and electrical characteristics. A number of methodologies in developing high-force-density IPMCs are also reported.
This paper presents an introduction to ionic polymer-metal composites and some mathematical modeling pertaining to them. It further discusses a number of recent findings in connection with ion-exchange polymer-metal composites (IPMCs) as biomimetic sensors and actuators. Strips of these composites can undergo large bending and flapping displacement if an electric field is imposed across their thickness. Thus, in this sense they are large motion actuators. Conversely by bending the composite strip, either quasi-statically or dynamically, a voltage is produced across the thickness of the strip. Thus, they are also large motion sensors. The output voltage can be calibrated for a standard size sensor and correlated to the applied loads or stresses. They can be manufactured and cut in any size and shape. In this paper first the sensing capability of these materials is reported. The preliminary results show the existence of a linear relationship between the output voltage and the imposed displacement for almost all cases. Furthermore, the ability of these IPMCs as large motion actuators and robotic manipulators is presented. Several muscle configurations are constructed to demonstrate the capabilities of these IPMC actuators. This paper further identifies key parameters involving the vibrational and resonance characteristics of sensors and actuators made with IPMCs. When the applied signal frequency varies, so does the displacement up to a critical frequency called the resonant frequency where maximum deformation is observed, beyond which the actuator response is diminished. A data acquisition system was used to measure the parameters involved and record the results in real time basis. Also the load characterizations of the IPMCs were measured and it was shown that these actuators exhibit good force to weight characteristics in the presence of low applied voltages. Finally reported are the cryogenic properties of these muscles for potential utilization in an outer space environment of a few Torrs and temperatures of the order of −140 degrees Celsius. These muscles are shown to work quite well in such harsh cryogenic environments and thus present a great potential as sensors and actuators that can operate at cryogenic temperatures.
This paper, the second in a series of four review papers to appear in this journal, presents a detailed description of various techniques and experimental procedures in manufacturing ionic polymer-metal composites (IPMCs) that, if fully developed, can be used as effective biomimetic sensors, actuators and artificial muscles as well as fully electroded with embedded electrodes for fuel cells. The performance of IPMCs manufactured by different manufacturing techniques are presented and compared. In particular, a number of issues such as force optimization using the Taguchi design of experiment technique, effects of different cations on electromechanical performance of IPMCs, electrode and particle size and distribution control, manufacturing cost minimization approaches, scaling and three-dimensional (3D) muscle production issues and heterogeneous composites by physical loading techniques are also reviewed and discussed.
This paper, the last in a series of four review papers to appear in this journal, presents some critical applications using ionic polymer-metal composites (IPMCs). Industrial and biomedical applications of IPMCs are identified and presented along with brief illustration.
Certain fluorinated ion-exchange membranes, when swollen and suitably plated by conducting electrodes, display a spontaneous curvature increasing with the applied field E (1) . There is also an inverse effect, where an imposed curvature induces an electric field (in open circuit conditions). We present here a compact description of these effects in the linear regime, and in static conditions: this is based on linear irreversible thermodynamics, with two driving forces (E and a water pressure gradient p ∇ ) and two fluxes (electric current and water current). We also give some qualitative estimates of the three Onsager coefficients which come into play.
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