In the presence of {[K.18-Crown-6]Br 3 } n , a unique tribromide reagent, trimethylsilyl (TMS) ethers, tetrahydropyranyl (THP) ethers, and alcohols were oxidized to their corresponding aldehydes and ketones in H 2 O 2 . One-pot deprotection and oxidation of TMS ethers/THP ethers were performed directly and the conversion was complete. Avoiding the isolation of the corresponding alcohol as an intermediate step, the direct transformation of such substrates to carbonyls is the main aim of this work. {[K.18-Crown-6]Br 3 } n regeneration was performed via the addition of Br 2 to the residue of the reaction and recrystallization in acetonitrile.
Various organic solid acids/NaNO 2 were used as effective oxidizing agents for the oxidation of urazoles and bis-urazoles to their corresponding triazolinediones under mild and heterogeneous conditions at room temperature with good-to-excellent yields.
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