The threat of oil pollution increases with the expansion of oil exploration and production activities, as well as the industrial growth around the world. The study on the treatment of oily wastewater is a critical issue to the environmental protection as oil caused problems to the wastewater treatment facilities. Although oil particles can efficiently be removed by advanced technologies, the treatments are usually expensive and difficult to maintain. Adsorption and coalescence filtration are promising choice of treatment for its simplicity, effectiveness, and feasibility when appropriate sorbent is used. This review discusses the recent papers on the use of natural fibrous sorbent for removal of oil from wastewater, and its current development. With their excellent oil removal properties, environmental friendliness, easy availability, and feasibility, natural fibrous sorbents are an attractive alternative for oily wastewater treatment.
Palm kernel shell (PKS) core fibers, an agricultural waste, were chemically modified using N(3chloro2hydroxypropyl) trimethylammonium chloride (CHMAC) as a quaternizing agent. The potential of quaternized palm kernel shell (QPKS) as an adsorbent for fluoride in an aqueous solution was then studied. The quaternized palm kernel shell (QPKS) core fibers were characterized using Fourier transform infrared spectroscopy (FTIR) and a scanning electron microscope (SEM). The effect of various factors on the fluoride sequestration was also investigated. The results showed that with an increase in the adsorbent amount and contact time, the efficiency of fluoride removal was improved. The maximum fluoride uptake was obtained at pH 3 and a contact time of 4 h. The adsorption behavior was further investigated using equilibrium isotherms and kinetics studies. The results from these studies fit well into Freundlich, RedlichPeterson, and Sips isotherm's with a coefficient of determination (R2) of 0.9716. The maximum fluoride removal was 63%. For kinetics studies, the pseudo second order was the best fit for fluoride, with an R2 of 0.999. These results suggest that QPKS has the potential to serve as a lowcost adsorbent for fluoride removal from aqueous solutions.
With oil and grease content of 4000-8000 mg/l in palm oil mill effluent (POME), the commonly used ponding system often fails to produce treated effluent that meets the minimum standard of treated effluent. The present study investigates the efficiency of sago bark (SB) and esterified sago bark (ESB) for removal of emulsified oil from POME. Oil removal experiments were conducted at different batch experimental conditions: namely adsorbent dosage, contact time, temperature and pH. In overall, the oil removal efficiency of both SB and ESB increased with the increasing of sorbent dosage and contact time. 24-h oil adsorption test afforded oil removal efficiency of 57.77% (SB) and 80.23% (ESB).On the other hand, the oil removal efficiency of both SB and ESB decreased with the increasing temperature. Acidic pH was favorable pH condition for high oil removal efficiency in POME. There was a good correlation (R2 > 9.5) between experimental data and the intra-particle diffusion model for both SB and ESB. The adsorption of oil in POME using SB was best described by Freundlich isotherm (R2 = 0.998), indicating heterolayer adsorption of oil on SB. The adsorption of oil in POME using ESB was better represented using Langmuir isotherm (R2 = 0.992), indicating a monolayer adsorption of oil onto the ESB surface. In conclusion, ESB showed better potential for use as sorbent for removing emulsified oil from wastewater, particularly POME.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.