Carbon fiber-reinforced polymers are considered a promising composite for many industrial applications including in the automation, renewable energy, and aerospace industries. They exhibit exceptional properties such as a high strength-to-weight ratio and high wear resistance and stiffness, which give them an advantage over other conventional materials such as metals. Various polymers can be used as matrices such as thermosetting, thermoplastic, and elastomers polymers. This comprehensive review focuses on carbon fiber-reinforced thermoplastic polymers due to the advantages of thermoplastic compared to thermosetting and elastomer polymers. These advantages include recyclability, ease of processability, flexibility, and shorter production time. The related properties such as strength, modulus, thermal conductivity, and stability, as well as electrical conductivity, are discussed in depth. Additionally, the modification techniques of the surface of carbon fiber, including the chemical and physical methods, are thoroughly explored. Overall, this review represents and summarizes the future prospective and research developments carried out on carbon fiber-reinforced thermoplastic polymers.
The objective of this work was to prepare and characterize a new and highly efficient modified membrane by in situ interfacial polymerization on porous polysulfone supports. The process used m-phenylenediamine and trimesoyl chloride in hexane, incorporating silver oxide Ag2O nanoparticles of varied concentrations from 0.001 to 0.1 wt%. Ag2O nanoparticles were prepared at different sizes varying between 20 and 50 nm. The modified membranes were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), atomic force microscopy (AFM), transmission electron microscopy (TEM), and contact angle measurement. The results showed a smooth membrane surface and average surface roughness from 31 to 74 nm. Moreover, hydrophilicity improved and the contact angle decreased to 41° at 0.009 wt% silver oxide. The performances of the developed membranes were investigated by measuring permeate fluxes and salt rejection capability by passing NaCl solutions (2000 ppm) through the membranes at 225 psi. The results showed that the flux increased from 26 to 40.5 L/m2 h, while the salt rejection was high, at 99 %, with 0.003 wt% Ag2O nanoparticles.
Polyamide thin-film composite (TFC) was fabricated on polysulfone (PS-20) base by interfacial polymerization of aqueous m-phenylenediamine (MPD) solution and 1,3,5-benzenetricarbonyl trichloride (TMC) in hexane organic solution. Multi-wall carbon nanotubes (MWCNT) were carboxylated by heating MWCNT powder in a mixture of HNO 3 and H 2 SO 4 (1:3 v/v) at 70°C under constant sonication for different periods. Polyamide nanocomposites were prepared by incorporating MWCNT and the carboxylated MWCNT (MWCNT-COOH) at different concentrations (0.001-0.009 wt%). The developed composites were analyzed by Fourier transform infrared spectroscopy-attenuated total reflection, scanning electron microscopy, transmission electron microscopy, contact angle measurement, determination of salt rejection and water permeate flux capabilities. The surface morphological studies displayed that the amalgamation of MWCNT considerably changed the surface properties of modified membranes. The surface hydrophilicity was increased as observed in the enhancement in water flux and pure water permeance, due to the presence of hydrophilic nanotubes. Salt rejection was obtained between 94 and 99% and varied water flux values for TFC-reference membrane, pristine-MWCNT in MPD, pristine-MWCNT in TMC and MWCNT-COOH in MPD were 20.5, 38, 40 and 43 L/m 2 h. The water flux and salt rejection performances revealed that the MWCNT-COOH membrane was superior membrane as compared to the other prepared membranes.
Fresh water scarcity and pollution turn out to be a most serious issue throughout the world due to the rapid population growth. The application of nanomaterials (NMs) for the removal of pollutants from water has attracted significant attention. The nanofiltration membrane was fabricated through the evaporative casting (EC) method using multiwalled carbon nanotubes (MWCNT) and chitosan (CHIT) as the surfactant to enable water purification. The developed EC membrane properties were characterized in mechanical, surface charging (zeta potential), surface morphology, and hydrophobicity properties. Results demonstrated that incorporation of MWCNT and the biopolymers (chitosan) resulted in suitable developments in mechanical properties of the membrane. For example, the membrane has shown values for tensile strength (28 ± 1 MPa), elongation (10.2 ± 1.2%), Young’s modulus (1.2 ± 0.1 GPa), and toughness of (1.9 ± 0.2 J/g). When more significant changes were investigated on the surface morphology of the EC membrane, it was observed that the pores on the surface morphology of the EC membrane decreased as the evaporative casting method was used. Moreover, the permeability of the membrane towards water, inorganic salts, and pH effect on salt rejections was studied using the NF/RO system. These established nanocomposite membranes signify the promising candidates for fresh water desalination and elimination of organic impurities.
Our goal is to develop a structural ceramic for high-temperature applications in which silicon carbide-based materials (SiCs) are used as matrix composites. The potential of SiCs to deposit a mixture of SiC and zirconium diboride (ZrB2) plasma spray coating is analyzed. To deposit thermal barrier layers containing up to 50 vol.% SiC, a high-pressure plasma spray (HPPS) process was used. Although the SiC cannot be deposited by thermal spray, a mixture of SiC and zirconium diboride (ZrB2) was deposited because these two compounds form a eutectic phase at a temperature below SiC decomposition. The preference was two different forms, 3 mm and 1 mm, of graphite substrates with different thickness values. A comparison of the morphology of SiC-ZrB2 coatings before and after thermal treatment was performed by applying heat to the surface of a gas torch and traditional furnace between 800 °C and 1200 °C. The growth of the oxide scale was calculated with X-ray diffraction (XRD), scanning electron microscopy (SEM)/energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), and density. The oxide scale consists of a SiO2 layer with ZrO2 groups. The findings indicate a greater potential for the studied material in protecting against high-temperature oxidation and in a wide variety of aerospace applications.
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