Summary The goal of this research was to develop methods for acquiring reservoir pressure and temperature data near the wellbore and farther out into the formation and to correlate such information to fracture connectivity and geometry. Existing reservoir-characterization tools allow pressure and temperature to be measured only at the wellbore. The development of temperature- and pressuresensitive nanosensors will enable in-situ measurements within the reservoir. This paper provides the details of the experimental work performed in the process of developing temperature nanosensors. The study investigated the parameters involved in the mobility of nanoparticles through porous and fractured media. These parameters include particle size or size distribution, shape, and surface charge or affinity to rock materials. The principal findings of this study were that spherically shaped nanoparticles of a certain size and surface charge compatible with that expected in formation rock are most likely to be transported successfully, without being trapped because of physical straining, chemical, or electrostatic effects. We found that tin-bismuth (Sn-Bi) nanoparticles of 200 nm and smaller were transported through Berea sandstone. Larger particles were trapped at the inlet of the core, indicating that there was an optimum particle size range. We also found that the entrapment of silver (Ag) nanowires was primarily because of their shape. This conclusion was supported by the recovery of the spherical Ag nanoparticles with the same surface characteristics through the same porous media used during the Ag nanowires injection. The entrapment of hematite nanorice was attributed to its affinity to the porous matrix caused by surface charge. The hematite coated with surfactant (which modified its surface charge to one compatible with flow media) flowed through the glass beads, emphasizing the importance of particle surface charge. Preliminary investigation of the flow mechanism of nanoparticles through a naturally fractured greywacke core was conducted by injecting fluorescent silica microspheres. We found that silica microspheres of different sizes (smaller than the fracture opening) could be transported through the fracture. We demonstrated the possibility of using microspheres to estimate fracture aperture by injecting a polydisperse microsphere sample. It was observed that only spheres of 20 μm and smaller were transported. This result agreed reasonably well with the measurement of hydraulic fracture aperture (27 μm), as determined by the cubic law.
The goal of this research was to develop methods of acquiring data about reservoir pressure and temperature, near the wellbore and far out in the formation, and correlating such information to fracture connectivity and geometry. Existing reservoir characterization tools allow for pressure and temperature to be measured only at the wellbore. The development of temperature-and pressure-sensitive nanosensors will enable in-situ measurements within the reservoir. This paper provides the details of the experimental work performed in the process of developing temperature and pressure nanosensors. The study investigated parameters involved in the mobility of nanoparticles through porous and fractured media. These parameters include particle size or size distribution, shape and surface charge or affinity to rock materials.The principal findings of this study were that spherically shaped nanoparticles with surface charge compatible with that expected in porous media are most likely to be transported successfully through formation rock, without being trapped due to physical straining, chemical or electrostatic effects. Silica nanoparticles were passed through Berea sandstone and long slimtube sand-packs without difficulty. We found that tin-bismuth nanoparticles of 200 nm and smaller were transported through Berea sandstone. Larger particles were trapped at the inlet of the core, indicating that there was an optimum particle size range. We also found that the entrapment of silver nanowires was primarily due to their shape. This conclusion was supported by the recovery of the spherical silver nanoparticles with the same surface characteristics. The entrapment of hematite nanorice was attributed to its affinity to the porous media caused by surface charge. The hematite coated with surfactant (which modified its surface charge to one compatible with flow media) flowed through the glass beads, emphasizing the importance of particles surface charge.Preliminary investigation of the flow mechanism of nanoparticles through a naturally fractured greywacke core was conducted by injecting fluorescent silica microspheres. We found that silica microspheres of different sizes (smaller than fracture opening) could be transported through the fracture. We demonstrated the possibility of using microspheres to estimate fracture aperture by injecting a polydisperse microsphere sample. It was observed that only spheres of 20 µm and smaller were transported. This result agreed reasonably well with the measurement of hydraulic fracture aperture (27 μm) as determined by the cubic law.
This manuscript reports the industry's first proven reservoir nanoagents' design and describes a successful multi-well field trial using these inexpensive and environmentally friendly nanoparticles that offer an important advantage of fast and cheap fluorometric detection. Our fundamental nanoparticle tracer template, A-Dots or Arab-D dots, is intentionally geared towards the harsh but prolific Arab-D carbonate reservoir environment of 100°C temperature, 150,000 ppm salinity, and an abundant presence of divalent ions in the connate water. The A-Dots were manufactured on a scale of one metric ton from affordable and easily available commodity chemicals. They were injected into a watered-out part of the field and monitored at four nearby producer wells for two years. Monitoring of four neighbouring producer wells over a period of 26 months confirmed nanoparticles' breakthrough at a single producer nearly 500 m from the injector at the reservoir level, thus, proving the nanoparticles' mobility and transport capability. The maximum concentration of the nanoagent in produced water was observed about 10 months after the injection matching the behavior of conventional small-molecule tracers used in the same pair of wells previously. The rate of A-Dots production correlated with the rate of water injection at the original injector well and followed it closely with a 10-month delay. This test bolstered our previous observations of satisfactory recovery of A-Dots in a single-well test by confirming their reservoir stability on industry relevant time scales and demonstrating the feasibility of their industrial production. The importance of this accomplishment is not in how sophisticated the sensing functionality of the tracer design is but rather in the nanoparticle stability, mobility, scalability, and field application potentials. Our findings render the concept of having active, reactive, and even communicative, in-situ reservoir nanoagents for underground sensing and intervention a well anticipated near-future reality.
nanoparticle silica deoxyribonucleic acid (DNA) thermochromic inverse problem a b s t r a c t Nanoparticle tracers are being investigated as a potential tool to measure temperature distributions in subsurface reservoirs. If the temperature distributions could be measured more precisely, this would greatly enhance the ability to estimate other reservoir properties, which would in turn inform reservoir engineering and field management decisions. Work toward two distinct but parallel objectives are described here. The first is to rank the informativity of various tracer candidates using modeling. The second is to develop temperature sensitive tracers experimentally, such that they would be capable of characterizing fracture properties and temperature distribution.The design of temperature-sensitive tracers is built around the design of the temperature sensing mechanism. In other words, the mechanism by which temperature is measured and the form and resolution of the resulting data, or response, have a profound impact on how informative that tracer can be about thermal breakthrough. Therefore, it is important to model the responses of candidate tracers in the context of an inverse problem to determine their relative informativity. In order to quantify tracer informativity for the simplified case in which the reservoir consists of a single parallel-plate fracture, one-dimensional analytical models were used to calculate the responses of four tracer types: conservative solute tracer, dye-releasing nanotracer, threshold nanoreactor, and temperature-time tracer (TTT). Inverse modeling was performed for various scenarios, and thermal breakthrough curves were calculated for each solution found. Tracers investigated in this study were found to perform very well, with small ranges of uncertainty for both thermal breakthrough forecasting and fracture property estimation. This was because the problem was highly constrained by defining the reservoir as a single fracture. For more realistic reservoir models consisting of complex fracture networks, it is expected that the uncertainty ranges would be larger and that all three temperature-sensitive tracers investigated here will outperform conservative solute tracers because their responses contain information about the temperature distribution.Experiments were performed to evaluate several potential nanosensor candidates for their temperaturesensitivity and to investigate particle mobility through porous and fractured media. Temperature-sensitive particles investigated in this study include the irreversible thermochromic, dye-attached silica and silicaprotected DNA particles. A combined heat and flow test confirmed the temperature-sensitivity of the irreversible thermochromic particles by observing the color change. A detectable change in the fluorescent emission spectrum of the dye-attached silica particles upon heating was observed.The processing and detection of silica-encapsulated DNA particles with hydrofluoric acid chemistry was tested. A protocol to release the DNA by disso...
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