Future generations require more efficient and localized processes for energy conversion and chemical synthesis. The continuous on-site production of hydrogen peroxide would provide an attractive alternative to the present state-of-the-art, which is based on the complex anthraquinone process. The electrochemical reduction of oxygen to hydrogen peroxide is a particularly promising means of achieving this aim. However, it would require active, selective and stable materials to catalyse the reaction. Although progress has been made in this respect, further improvements through the development of new electrocatalysts are needed. Using density functional theory calculations, we identify Pt-Hg as a promising candidate. Electrochemical measurements on Pt-Hg nanoparticles show more than an order of magnitude improvement in mass activity, that is, A g(-1) precious metal, for H2O2 production, over the best performing catalysts in the literature.
Electrochemically converting nitrate, a widespread water pollutant, back to valuable ammonia is a green and delocalized route for ammonia synthesis, and can be an appealing and supplementary alternative to the Haber-Bosch process. However, as there are other nitrate reduction pathways present, selectively guiding the reaction pathway towards ammonia is currently challenged by the lack of efficient catalysts. Here we report a selective and active nitrate reduction to ammonia on Fe single atom catalyst, with a maximal ammonia Faradaic efficiency of ~ 75% and a yield rate of up to ~ 20,000 μg h−1 mgcat.−1 (0.46 mmol h−1 cm−2). Our Fe single atom catalyst can effectively prevent the N-N coupling step required for N2 due to the lack of neighboring metal sites, promoting ammonia product selectivity. Density functional theory calculations reveal the reaction mechanisms and the potential limiting steps for nitrate reduction on atomically dispersed Fe sites.
The direct electrochemical synthesis of hydrogen peroxide is a promising alternative to currently used batch synthesis methods. Its industrial viability is dependent on the effective catalysis of the reduction of oxygen at the cathode. Herein, we study the factors controlling activity and selectivity for H2O2 production on metal surfaces. Using this approach, we discover two new catalysts for the reaction, Ag–Hg and Pd–Hg, with unique electrocatalytic properties both of which exhibit performance that far exceeds the current state-of-the art.
Precise control of elemental configurations within multimetallic nanoparticles (NPs) could enable access to functional nanomaterials with significant performance benefits. This can be achieved down to the atomic level by the disorder-to-order transformation of individual NPs. Here, by systematically controlling the ordering degree, we show that the atomic ordering transformation, applied to AuCu NPs, activates them to perform as selective electrocatalysts for CO reduction. In contrast to the disordered alloy NP, which is catalytically active for hydrogen evolution, ordered AuCu NPs selectively converted CO to CO at faradaic efficiency reaching 80%. CO formation could be achieved with a reduction in overpotential of ∼200 mV, and catalytic turnover was enhanced by 3.2-fold. In comparison to those obtained with a pure gold catalyst, mass activities could be improved as well. Atomic-level structural investigations revealed three atomic gold layers over the intermetallic core to be sufficient for enhanced catalytic behavior, which is further supported by DFT analysis.
Bimetallic catalysts are promising for the most difficult thermal and electrochemical reactions but modeling the many diverse active sites on polycrystalline samples is an open challenge. We present a general framework for addressing this complexity in a systematic and predictive fashion. Active sites for every stable low-index facet of a 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 sites. The activity of these sites is explored in parallel using a neural-network based surrogate model to share information between the many Density Functional Theory (DFT) relaxations, resulting in activity estimates with an order of magnitude fewer explicit DFT calculations. Sites with interesting activity were found and provide targets for follow-up calculations. This process was applied to the electrochemical reduction of CO 2 on nickel gallium bimetallics and indicated that most facets had similar activity to Ni surfaces, but a few exposed Ni sites with a very favorable on-top CO configuration. This motif emerged naturally from the predictive modeling and represents a class of intermetallic CO 2 reduction catalysts. These sites rationalize recent experimental reports of nickel gallium activity and why previous materials screens missed this exciting material. Most importantly these methods suggest that bimetallic catalysts will be discovered by studying facet reactivity and diversity of active sites more systematically.
The one-step electrochemical synthesis of H 2 O 2 is an on-site method that reduces dependence on the energy-intensive anthraquinone process. Oxidized carbon materials have proven to be promising catalysts due to their low cost and facile synthetic procedures. However, the nature of the active sites is still controversial, and direct experimental evidence is presently lacking. Here, we activate a carbon material with dangling edge sites and then decorate them with targeted functional groups. We show that quinone-enriched samples exhibit high selectivity and activity with a H 2 O 2 yield ratio of up to 97.8 % at 0.75 V vs. RHE. Using density functional theory calculations, we identify the activity trends of different possible quinone functional groups in the edge and basal plane of the carbon nanostructure and determine the most active motif. Our findings provide guidelines for designing carbon-based catalysts, which have simultaneous high selectivity and activity for H 2 O 2 synthesis.
RuO 2 has been reported to reduce CO 2 electrochemically to methanol at low overpotential. Herein, we use density functional theory (DFT) to gain insight into the mechanism for CO 2 reduction on RuO 2 (110). We investigate the thermodynamic stability of various surface terminations in the electrochemical environment and find CO covered surfaces to be particularly stable, although their formation might be kinetically limited at mildly reducing conditions. We identify the lowest free energy pathways for CO 2 reduction to formic acid (HCOOH), methanol (CH 3 OH) and methane (CH 4 ) on partially reduced RuO 2 (110) covered with 0.25 and 0.5 ML of CO*. We find CO 2 is reduced to formic acid, which is further reduced to methanol and methane. At 0.25 ML CO* the reduction of formate (OCHO*) to formic acid is the thermodynamically most difficult step and becomes exergonic at potentials below -0.43 V vs. the reversible hydrogen electrode (RHE). On the other hand, at 0.5 ML CO*, the reduction of formic acid to H 2 COOH* is the thermodynamically most difficult step and becomes exergonic at potentials below -0.25 V vs.RHE. We find that CO 2 reduction activity on RuO 2 changes with CO coverage, which suggests that CO coverage can be used as a tool to tune the CO 2 reduction activity. We show the mechanism for CO 2 reduction on RuO 2 to be different from that on Cu. On Cu, hydrocarbons are formed at high Faradaic efficiency through reduction of CO* at ~1 V overpotential, while on RuO 2 , methanol and formate are formed through reduction of formic acid at lower overpotentials. Using our understanding of the CO 2 reduction mechanism on RuO 2 , we suggest reduction of formic acid on RuO 2 , which should lead to methanol and methane production at relatively low overpotentials.
One of the main challenges associated with the electrochemical CO or CO 2 reduction is poor selectivity toward energetically rich products. In order to promote selectivity toward hydrocarbons and alcohols, most notably, the hydrogen evolution reaction (HER) should be suppressed. To achieve this goal, we studied intermetallic compounds consisting of transition metal (TM) elements that can reduce CO (Ru, Co, Rh, Ir, Ni, Pd, Pt, and Cu) separated by TM and post transition metal elements (Ag, Au, Cd, Zn, Hg, In, Sn, Pb, Sb, and Bi) that are very poor HER catalysts. In total, 34 different stable binary bulk alloys forming from these elements have been investigated using density functional theory calculations. The electronic and geometric properties of the catalyst surface can be tuned by varying the size of the active centers and the elements forming them. We have identified six different potentially selective intermetallic surfaces on which CO can be reduced to methanol at potentials comparable to or even slightly positive than those for CO/CO 2 reduction to methane on Cu. Common features shared by most of the selective alloys are single TM sites. The role of single sites is to block parasitic HER and thereby promote CO reduction.
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