Recently a new class of metal alloys, of single-phase multicomponent composition at roughly equal atomic concentrations ("equiatomic"), have been shown to exhibit promising mechanical, magnetic, and corrosion resistance properties, in particular, at high temperatures. These features make them potential candidates for components of next-generation nuclear reactors and other high-radiation environments that will involve high temperatures combined with corrosive environments and extreme radiation exposure. In spite of a wide range of recent studies of many important properties of these alloys, their radiation tolerance at high doses remains unexplored. In this work, a combination of experimental and modeling efforts reveals a substantial reduction of damage accumulation under prolonged irradiation in single-phase NiFe and NiCoCr alloys compared to elemental Ni. This effect is explained by reduced dislocation mobility, which leads to slower growth of large dislocation structures. Moreover, there is no observable phase separation, ordering, or amorphization, pointing to a high phase stability of this class of alloys.
Irradiation-induced damage accumulation in Ni 0.8 Fe 0.2 and Ni 0.8 Cr 0.2 alloys are investigated using molecular dynamics (MD) simulations to assess possible enhanced radiation-resistance in these face-centered cubic (fcc), single-phase, concentrated solid-solution alloys, as compared with pure fcc Ni. The Ni 0.8 Cr 0.2 and Ni 0.8 Fe 0.2 alloys demonstrate higher radiation resistance compared to Ni. The total number of point defects produced in Ni 0.8 Cr 0.2 and Ni 0.8 Fe 0.2 is approximately 2.5 and 1.4 times lower than in Ni, respectively, due to efficient defect recombination in the chemically disordered alloys. Both interstitial and vacancy clusters are formed in all three materials. In Ni, large interstitial clusters are produced; whereas in Ni 0.8 Cr 0.2 , smaller interstitial clusters are produced but with a higher number. This indicates a higher mobility of interstitials in Ni compared to Ni 0.8 Cr 0.2. Moreover, Ni 0.8 Cr 0.2 shows better radiation resistance than Ni 0.8 Fe 0.2. Larger interstitial clusters and 1.7 times higher numbers of accumulated point defects are observed in Ni 0.8 Fe 0.2 , in comparison with Ni 0.8 Cr 0.2. Due to the low mobility of vacancies on the MD time scales, they are found primarily as single point defects and small clusters in all materials. While performance improvement is observed in the alloys, the difference in irradiation response between Ni 0.8 Cr 0.2 and Ni 0.8 Fe 0.2 indicates the importance of element choice to achieve the desired property.
Understanding alloying effects on the irradiation response of structural materials is pivotal in nuclear engineering. To systematically explore the effects of Fe concentration on the irradiation-induced defect evolution and hardening in face-centered cubic Ni-Fe binary solid solution alloys, single crystalline Ni-xFe (x=0-60 at%) alloys have been grown and irradiated with 1.5 MeV Ni ions. The irradiations have been performed over a wide range of fluences from 310 13 to 310 16 cm-2 at room temperature. Ion channeling technique has shown reduced damage accumulation with increasing Fe concentration in the low fluence regime, which is consistent to the results from molecular dynamic simulations. No irradiation-induced compositional segregation was observed in atom probe tomography within the detection limit, even in the samples irradiated with high fluence Ni ions. Transmission electron microscopy analyses have further demonstrated that the defect size significantly decreases with increasing Fe concentration, indicating a delay in defect evolution. Furthermore, irradiation induced hardening has been measured by nanoindentation tests. Ni and the Ni-Fe alloys have largely different initial hardness, but they all follow a similar trend for the increase of hardness as a function of irradiation fluence.
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