Phosphorus (P) is an important critical material essential for crops cultivation and animal husbandry. Effective phosphorous recycling is considered one of the most significant factors in alleviating its criticality. However, despite the importance of phosphorous recycling, its sustainability is not studied extensively. This paper aims to answer the question if recycling of phosphorus is an environmentally sustainable option. To address this problem, two issues are analyzed in this paper: energy consumption and greenhouse gas (GHG) emissions in phosphorous recycling. The analysis was performed by simulating mass and energy flows in the global phosphorus supply chain (from mining to recycling) in order to understand and analyze its environmental impact in 2000-2050. The results of simulation show that around 82% of recycled phosphorous originates from manure. Moreover, the calculations indicate that about 70% of total GHG emissions from phosphorous recycling is caused by wastewater processing. In addition, the results show that phosphorous obtained from recycled wastewater constitutes only 2% of the whole amount recovered in the recycling process. Therefore, the obtained results show a clear need for a detailed analysis of the sustainability of phosphorous recycling processes. Moreover, the analysis of scenarios of phosphorus consumption indicates that GHG emissions increase slowly in the mining phase and grow exponentially in the recycling stage.The main finding of this paper contradicts the general opinion about environmental friendliness of recycling. It shows that phosphorus recycling is not a sustainable solution in a longer perspective.
The recycling of scrap is one of the common approaches aiming at reduction of mining-based production of critical metals and mitigation of their supply risk as well as processing-related environmental impact. The number of currently available end-of-life vehicles (ELVs) indicates—significant potential for critical metals recycling, especially niobium (Nb). Therefore, the quantification of environmental impact of niobium recovery starts to be an important issue in assessment of sustainability of large-scale recycling processes. In this paper, we assess energy consumption and greenhouse gas (GHG) emissions in individual stages of niobium supply chain in the automotive industry over the period 2010–2050. The different stages including mining, production and recycling are analyzed using dynamic simulation. The results show the majority of the consumed energy (45% of energy demand in niobium supply chain) is used in the primary production stage. This stage also contributes to 72% of total gas emissions of supply chain over the period 2010–2050. Mining of niobium consumes up to 36% of energy and generates ca. 21% of GHG emissions. While, in recycling stage, the secondary production of niobium requires 19% of supply chain energy and generates 7% of gas emissions. The detailed calculations show that recycling of niobium could save around 133–161 m GJ energy between 2010 and 2050. The recycling would also contribute to the reduction of 44–53 mt CO2-eq in the same period. It shows around 18% reduction of annual emissions between 2010 and 2050 thanks to reuse of niobium in secondary production rather than primary production.
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