a b s t r a c tCarob kibbles are an important renewable source of valuable compounds, such as fermentable sugars and phenolic compounds. However, the selective recovery of these compounds is not a trivial task. In this work, a strategy was developed to enable the recovery of both classes of compounds by means of a water-based extraction.One-step extraction recovered only approximately 20% of the phenolic compounds, corresponding to an extraction yield of 0.6 g Gallic acid equivalents (GAE)/100 g dry mass of carob kibbles. The obtained extract contained a significant amount of carbohydrates (110 g/L). The alternative two-step extraction developed enabled higher compound selectivity together with an increase in the yield of the phenolic compounds to about 70%, corresponding to 1.9 g GAE /100 g carob dry matter.The two-step extraction was easily scaled-up and is an effective method to obtain significantly separated carbohydrates and polyphenol-rich streams that can be further processed, e.g., in biorefineries or food industries, respectively.

a b s t r a c tCarob kibbles are a low-cost and renewable source of economically relevant phenolic compounds (high value catechin and its derivatives and gallic acid) and abundant in small sugars. This work aims at producing two distinct natural extracts from carob kibbles, one extract enriched in catechin and its derivatives for the nutraceuticals market and an extract enriched in sugars for the food industry. This valorisation strategy involves an integrated process based on membrane technology that fulfils the zero discharge principle and may be applied to other agro-industrial by-products. Different aqueous extraction schemes were considered (a one-step process and a two-steps approach). The aqueous extracts obtained were fractionated by diananofiltration and the fractions obtained were evaluated in terms of their content in target products. An integrated scheme for production of fractionated extracts is proposed based on the experimental work developed assuring, simultaneously, a minimal use of resources and emission of waste.Ó 2015 Published by Elsevier B.V.

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