Controlling the properties of nanostructured zinc oxide (ZnO) is an interesting way to broaden its multifunctionality. ZnO nanostructured films were grown on glass substrates under different conditions by a simple two-step wet chemical method. A low-cost successive ionic layer adsorption and reaction (SILAR) method was used to grow ZnO seed layers at 80 C. Then, different hierarchical based ZnO nanostructured thin films were deposited onto the ZnO seed layers by chemical bath deposition (CBD).The influence of deposition time (t D ) and pH on the surface morphology, wettability behavior, structural and optical properties of the ZnO nanostructured films were systematically investigated. The structural, morphological, optical and wetting properties were studied by X-ray diffraction (XRD), field emission scanning microscopy (FE-SEM), UV-Vis spectrophotometer, and water contact angle (WCA) measurement, respectively. The surface morphology revealed a complex and orientated hierarchical based ZnO nanostructured films with diverse shapes from hexagonal nanorods to hexagonal nanoplates and even much more complex plates/rods and flower-like shapes by changing deposition time and pH of the precursor. XRD results confirm the synthesis of nanostructured ZnO of the hexagonal structure with a preferential orientation along the (002) lattice plane. The average crystallite size, D, is altered between 41.41 to 68.43 nm dependent on the morphology of the ZnO film and pH of the precursor. At pH 6.5, the films are hydrophilic for 10 h # t D # 6 h and hydrophobic for 6 h < t D < 10 h. The wetting properties of the films were enhanced by increasing or decreasing pH around 6.5. Morphology and thickness of the ZnO nanostructure could efficiently control the transmittance, absorbance, optical band gap, and the extinction coefficient of the films. The optical band gap is blue shifted from 2.45 to 3.62 eV@pH 6.5 as the deposition time increased from 2 to 8 h and blue shifted from 2.72 to 3.62 eV@8 h as the pH value increased from 5.5 to 6.5. The existence of stable hydrophobic zinc oxide nanostructured films at room temperature at a large-scale and with band gaps around 3.62 eV supports their use in selfcleaning and gas sensing applications.
Thin films of ZnO and ZnO/carbon nanotubes (CNTs) are prepared and used as CO2 gas sensors. The spray pyrolysis method was used to prepare both ZnO and ZnO/CNTs films, with CNTs first prepared using the chemical vapor deposition method (CVD). The chemical structure and optical analyses for all the prepared nanomaterials were performed using X-ray diffraction (XRD), Fourier transformer infrared spectroscopy (FTIR), and UV/Vis spectrophotometer devices, respectively. According to the XRD analysis, the crystal sizes of ZnO and ZnO/CNTs were approximately 50.4 and 65.2 nm, respectively. CNTs have average inner and outer diameters of about 3 and 13 nm respectively, according to the transmitted electron microscope (TEM), and a wall thickness of about 5 nm. The detection of CO2 is accomplished by passing varying rates of the gas from 30 to 150 sccm over the prepared thin-film electrodes. At 150 sccm, the sensitivities of ZnO and ZnO/CNTs sensors are 6.8% and 22.4%, respectively. The ZnO/CNTs sensor has a very stable sensitivity to CO2 gas for 21 days. Moreover, this sensor has a high selectivity to CO2 in comparison with other gases, in which the ZnO/CNTs sensor has a higher sensitivity to CO2 compared to H2 and C2H2.
Nucleation energetics during homogeneous solidification in elemental metallic liquidsMelting and solidification of as-deposited and recrystallized Bi crystallites, deposited on highly oriented 002-graphite at 423 K, were studied using reflection high-energy electron diffraction ͑RHEED͒. Films with mean thickness between 1.5 and 33 ML ͑monolayers͒ were studied. Ex situ atomic force microscopy was used to study the morphology and the size distribution of the formed nanocrystals. The as-deposited films grew in the form of three-dimensional crystallites with different shapes and sizes, while those recrystallized from the melt were formed in nearly similar shapes but different sizes. The change in the RHEED pattern with temperature was used to probe the melting and solidification of the crystallites. Melting started at temperatures below the bulk melting point of Bi, T 0 = 544.5 K, and extended over a temperature range that depended on the size distribution of the crystallites. The as-deposited 1.5 ML film started to melt at T 0 − 50 K and melted completely at T 0 − 20 K. For films with higher coverage, the size distribution was observed to spread over a wider range with a larger mean value, resulting in a shift in the melting temperature range towards higher temperatures. Due to the shift in size distribution to higher values upon recrystallization, the recrystallized Bi crystallites showed a melting temperature range higher than that of the as-deposited crystallites. For the investigated conditions, all films were completely melted below or at T 0 of Bi. The characteristic film melting point, defined as the temperature at which the film melting rate with temperature is the fastest, showed a linear dependence on the reciprocal of the average crystallite radius, consistent with theoretical models. Of these models, the surface-phonon instability model best fits the obtained results. During solidification, the Bi films showed high amount of supercooling relative to T 0 of Bi. The amount of liquid supercooling was found to decrease linearly with the reciprocal of the average crystallite size.
To improve photoelectrochemical (PEC) water splitting, various ZnO nanostructures (nanorods (NRs), nanodiscs (NDs), NRs/NDs, and ZnO NRs decorated with gold nanoparticles) have been manufactured. The pure ZnO nanostructures have been synthesized using the successive ionic-layer adsorption and reaction (SILAR) combined with the chemical bath deposition (CBD) process at various deposition times. The structural, chemical composition, nanomorphological, and optical characteristics have been examined by various techniques. The SEM analysis shows that by varying the deposition time of CBD from 2 to 12 h, the morphology of ZnO nanostructures changed from NRs to NDs. All samples exhibit hexagonal phase wurtzite ZnO with polycrystalline nature and preferred orientation alongside (002). The crystallite size along (002) decreased from approximately 79 to 77 nm as deposition time increased from 2 to 12 h. The bandgap of ZnO NRs was tuned from 3.19 to 2.07 eV after optimizing the DC sputtering time of gold to 4 min. Via regulated time-dependent ZnO growth and Au sputtering time, the PEC performance of the nanostructures was optimized. Among the studied ZnO nanostructures, the highest photocurrent density (Jph) was obtained for the 2 h ZnO NRs. As compared with ZnO NRs, the Jph (7.7 mA/cm2) of 4 min Au/ZnO NRs is around 50 times greater. The maximum values of both IPCE and ABPE are 14.2% and 2.05% at 490 nm, which is closed to surface plasmon absorption for Au NPs. There are several essential approaches to improve PEC efficiency by including Au NPs into ZnO NRs, including increasing visible light absorption and minority carrier absorption, boosting photochemical stability, and accelerating electron transport from ZnO NRs to electrolyte carriers.
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