The nanoconfinement of water results in changes in water properties and nontraditional water flow behaviors. The determination of the interfacial interactions between water and hydrophobic surfaces helps in understanding many of the nontraditional behaviors of nanoconfined water. In this study, an approach for the identification of the viscosity of water interfaces with hydrophobic nanopores as a function of the nanopore diameter and water-solid (nanopore) interactions is proposed. In this approach, water in a hydrophobic nanopore is represented as a double-phase water with two distinct viscosities: water interface and water core. First, the slip velocity to pressure gradient ratio of water flow in hydrophobic nanopores is obtained via molecular dynamics (MD) simulations. Then the water interface viscosity is determined via a pressure gradient-based bilayer water flow model. Moreover, the core viscosity and the effective viscosity of water flow in hydrophobic nanopores are derived as functions of the nanopore diameter and water-solid interactions. This approach is utilized to report the interface viscosity, core viscosity, and effective viscosity of water flow in carbon nanotubes (CNTs) as functions of the CNT diameter. Moreover, using the proposed approach, the transition from MD to continuum mechanics is revealed where the bulk water properties are recovered for large CNTs.

In this study, a reduced micromorphic model for multiscale materials is developed. In the context of this model, multiscale materials are modeled with deformable microstructures. The deformation energy is formed depending on microstrain and macroscopic strain residual fields. The constitutive equations according to the reduced micromorphic model only depend on eight material coefficients for linear elastic materials. These material coefficients are related to the material micro/macro-stifnesses and the material's microstructural features. The wave dispersions in multiscale materials are then derived according to the reduced micromorphic model. It is revealed that this model can reflect nine dispersion curves (three acoustic modes and six optics) for a two-scale material. To demonstrate the effectiveness of the proposed model, the wave propagation characteristics, the band structure, and the absolute bandgap features of phononic materials are investigated. It is demonstrated that the reduced micromorphic model can effectively reflect the increase in the bandgap width with the increase in the filling factor in a composite phononic material with square lattices.

We put water flow under scrutiny to report radial distributions of water viscosity within hydrophobic and hydrophilic nanotubes as functions of the water-nanotube interactions ( ), surface wettability ( θ ), and nanotube size ( R ) using a proposed hybrid continuum-molecular mechanics. Based on the computed viscosity data, phase diagram of the phase transitions of confined water in nanotubes is developed. It is revealed that water exhibits different multiphase structures, and the formation of one of these structures depends on R parameters. A drag of water flow at the first water layer is revealed, which is conjugate to sharp increase in the viscosity and formation of an ice phase under severe confinement (R ≤ 3.5 nm) and strong water-nanotube interaction conditions. A vapor/vapor-liquid phase is observed at hydrophobic and hydrophilic interfaces. A state of confinement is revealed at which water exhibits different multiphase structures under the same flow rate. The derived viscosity functions are used to accurately determine factors of flow enhancement/inhibition of confined water.

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