Perovskite solar cells (PSCs) have drawn significant consideration as a competing solar cell technology because of the drastic advance in their power conversion efficiency (PCE) over the last two decades. The interfaces between the electron transport layer (ETL) and the absorber layer and between the absorber layer and the hole transport layer (HTL) have a major impact on the performance of the PSCs. In this paper, we have investigated the defect interfaces between ETL/absorber layer and absorber layer/HTL of calibrated experimental lead-based and lead-free PSCs. The influence of the defect interfaces is studied in order to find the optimum value for the maximum possible PCE. While the PCE has not been enhanced considerably for the lead-based, it is boosted from 1.76% to 5.35% for lead-free PSCs. Also, bulk traps were found to have minor role in comparison with interface traps for the lead-free cell while they have a significant impact for the lead-based cell. The results presented in this work would shed some light on designing interface defects of various types of practical PSC structures and demonstrates the crucial impact of the interface defects on lead-free vs lead-based PSCs. All simulation studies are performed by using SCAPS-1D simulator.
In the current research article, the two-dimensional, incompressible, steady fluid flow is considered. The heat transfer rate of water-based aggregated fluid between converging/diverging channels of shrinking/stretching walls due to the effects of thermal radiation has been examined. The strong static magnetic field is applied perpendicular to the radial direction. The modeled governing equations are transformed into non-linear dimensionless ordinary differential equations by considering appropriate similarity transformations. Since the obtained ODEs are strongly non-linear and the exact solution of these equations is not possible, thus we applied the numerical method RK4 combined with the shooting technique to handle the equations. The impacts of several influential parameters on velocity, temperature, and entropy generation profiles are examined graphically.
Energy security is one of the main factors in the development and diffusion of microgrid applications. In networks operating without storage, the operation of their systems is greatly affected by sudden load demand and intermittent generation fluctuations. The main purposes of using energy storage systems in microgrids are stabilizing the intermittent generation of renewable energy sources locally, to ensure that energy production matches energy demands, participating in the frequency regulation process, maintaining the energy balance between generation and demand in renewable energy microgrids, and increasing energy reliability. This study investigates the frequency and power balance of an isolated microgrid system, by including storage systems (battery and pump-hydro). Realistic data for wind and solar sources are used for the optimal tuning of the proportional-integral controller, using the integral of the absolute error criterion multiplied by time, with a Quasi-Newton method. Simulation studies have been carried out, to investigate the performance of the microgrid system, by including the hydroelectric power plant system with pump storage for 24 h, under various operating conditions. The results reveal that by including the storage units in the system, it exhibits a more consistent and smooth dynamic performance, using renewable energy efficiently.
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