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This report deals with converting the agriculture waste (rice straw) to environmental cleaner materials (biochar) using airless pyrolysis followed by eco-friendly activation. The biochar (p-Biochar) obtained after pyrolysis step (poorly active material) was activated using wet attrition method to give m-Biochar (highly active materials). The both p-Biochar and m-Biochar were characterized in detail and utilized for MB and CV dye removal from aqueous solution. Various parameters affecting the adsorption process such as dye concentration, adsorbent dose, contact time, temperature, NaCl dose and pH were investigated. The adsorption isotherm was well fitted using Langmuir isotherm, and the maximum adsorption capacity is 90.91 and 44.64 mg/g, for MB and CV dyes, respectively. The contact time data obtained showed that the two dyes were poorly adsorbed over p-Biochar. The equilibrium was reached quickly in 15 min for MB dye and 20 min for CV dye using the m-Biochar, and removal percent was 94.45 and 92.70% for MB and CV dyes, respectively. Moreover, the kinetic isotherm presented very well fitted by pseudo-second-order model. In addition, the adsorption percent increases with further increasing the pH value. Finally, we observed that m-Biochar highly adsorbs the MB dye compared with the CV dye over all experimental conditions.

Soil carbon (C) storage potential has received considerable attention for its role in climate change mitigation, and much research work has been devoted to studying the effect of land‐use change, including land abandonment, on carbon dynamics. A comparative analysis of soil organic carbon (SOC), easily extractable Bradford‐reactive soil protein (EE‐BRSP) and Bradford‐reactive soil protein (BRSP) was carried out at monthly intervals in a land‐use sequence including cultivated soils, forest soils, shrubs and pasture in northeast Spain. In general, greater seasonal variations of both EE‐BRSP and BRSP were found in soils with less carbon storage capacity. Turnover of glomalin into more stable C forms was associated with a small EE‐BRSP:BRSP ratio in better structured soils and BRSP was related to organic carbon, suggesting positive contributions to both the recalcitrant carbon pool and soil structure. This effect seemed to be more pronounced in August when more BRSP was found, probably because of high temperature and dry soils in which glomalin may react to preserve residual adsorbed water and provide better protection in soil microsites. The role of glomalin was further enhanced by the structural stability of aggregates (WSA) investigated in two aggregate fractions (0.25–2.00 and 2.00–5.60 mm), indicating its beneficial effect in aggregation and carbon storage potential. BRSP, SOC and WSA increased significantly (P < 0.001) along the transect and abandonment sequence; the largest WSA values were generally greater in summer in both aggregate fractions. However, values in cultivated soils were always smaller than in soils under shrubs and pasture. Similarly, soils with a smaller carbon pool had the largest proportion of carbon loss as CO2‐C when land use changes from vines to pasture. The role of aggregates in protecting organic carbon against mineralization was therefore postulated and highlighted the importance of soil monitoring after land abandonment.

Purpose: Shallow soils previously cultivated under terraced systems may change their properties after agricultural release and spontaneous plant colonization. Investigations were conducted in terraced fields (NE Spain) to prove that vegetation installed after the abandonment may generally improve soil properties by the formation of stable organic horizons. However, restriction in plant species along the natural vegetation succession and intensification of erosion processes may occur after abandonment depending on fire frequency and soil use history. Materials and methods: Ten environments with different plant covers under a Lithic Xerorthent were selected and erosion plots (Gerlach type) installed providing their best adaptability at the terrace scale. Selected soil environments represented the sequence of abandonment: from current poorly cultivated soils, soils under pasture, soils under shrubs, and soils under stands of pine and cork trees. Relevant rainfall events producing runoff and erosion were recorded from November 2011 to May 2012. Erosion rates and erosion components were analysed in sediments and water in order to monitor carbon, nitrogen and other nutrient removal by overland flow. Similarly, the physical and chemical properties of the soil environments under study were determined at the same time interval of runoff erosion. Results and discussion: Soils under pasture, vines and recently burnt pine forest produced the highest runoff followed by soils under shrubs and forest. However, eroded soil yields and nutrient removal were much higher in cultivated soils and soils in recently burnt sites, which had shown poorer soil properties with respect to soils abandoned for longer and preserved by fire. Fire-affected soil environments also showed a thinner organic horizon and reduced water retention. Although erosion rates and nutrient depletion were low in all environments with respect to other areas of Spain, higher splash than water erosion was an early warning indicator of the high susceptibility to degradation of these shallow soils. Conclusions: Results outlined that the renaturalization dynamics after agricultural abandonment are complex biophysical processes involving the parent material, depth to bedrock and other soil properties as well as the succession of vegetative cover and plant associations responsible for building a new soil mantle contrasting with erosion processes. Planning for management of land abandonment is strongly recommendedWe acknowledge the financial support for this study provided by the Research Project CGL2007-66644-C04-02 funded by the Spanish Government. The contribution of pre-doctoral grant BES-2008-010099 funded by the Ministry of Science and Innovation-MICIN enabled part of the research work and is also acknowledge

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