The use of encapsulating healing agents that allow the self-healing of concrete has emerged as a potential solution to the current decay and costly maintenance of concrete infrastructure; however, many healing agents are expensive. The objectives of this study were to develop a procedure for the production of urea–formaldehyde microcapsules of calcium nitrate and to evaluate the effects of the microcapsules on self-healing efficiency in concrete. Calcium nitrate was selected for microencapsulation, given its low cost and its effect on acceleration of the setting of unhydrated cement. The results indicated that the agitation rate and the temperature had a linear correlation with the microcapsule diameter and the shell wall thickness, respectively. A higher agitation rate resulted in a smaller microcapsule diameter, whereas a higher temperature resulted in a thinner shell wall. The morphology of all microcapsules synthesized was virtually the same throughout the experimental matrix, with the shell walls of all the microcapsules observed having a smooth exterior surface and a rough interior surface. All microcapsules produced were also observed to have a broad particle size distribution. This characteristic was attributed to the type of surfactant used in the process. Analysis of the effects of the microcapsules on the self-healing efficiency of concrete showed that the modulus of elasticity increased after healing for all concrete specimens prepared with self-healing agents. The largest increase in the modulus of elasticity was observed at a microcapsule content of 0.50%. The results also showed that concrete specimens into which microcapsules were incorporated at any concentration had greater surface resistivities than control specimens.
Self-healing concrete with microencapsulated calcium nitrate was investigated. The compressive strength of concrete admixed with microcapsules (as a percentage of the weight of the cement) was tested and compared with that of control specimens of the same mix design without microcapsules. Surface resistivity tests were conducted to quantify the surface permeability of the concrete specimens with and without microcapsules. The self-healing potential was measured by the modulus of elasticity test (ASTM C469), with measurements being taken before and after damage after 14 days. After the concrete was damaged by application of 80% of its ultimate load, all specimens were incubated by immersion in water. The results showed that the concentration of microcapsules added and the size of the microcapsules had a direct impact on the compressive strength of the concrete. Furthermore, the concrete specimens into which microcapsules were incorporated had greater surface resistivity than the control specimens. The recovery of the modulus of elasticity was analyzed according to the increase from the modulus of elasticity recorded after application of 80% of the sample’s ultimate load and the increase relative to the initial modulus of elasticity of the concrete in the virgin state. Overall, the results of this study indicated that although microcapsules caused a decrease in the compressive strength of the concrete, they enhanced the self-healing capability of the concrete that was produced. To take advantage of the benefits of microcapsules, the authors recommend that future work evaluate the use of a dispersing agent to reduce the amount of microcapsules needed in the mix.
This paper investigates the potential utilization of the Tunnel Boring Machine (TBM) muck generated from Doha’s Metro Gold Line in different construction applications. The properties of the raw TBM muck were studied, and the results were compared to the specifications of Qatari Construction Standards (QCS 2014) of concrete aggregates, fill material under buildings and road subgrades. Compared to the requirements of concrete aggregates, the results indicated that the gradation of the raw TBM muck does not comply with the QCS 2014 requirements, and hence, sieving and screening may be essential. Moreover, the tests’ results showed that the properties of the muck meet the requirements of the concrete coarse aggregates, except for the water absorption, loss by magnesium sulphate soundness, loss by Los Angeles abrasion and the acid-soluble sulphate. As fill material under buildings or road subgrades, the gradation of the TBM muck complies with the QCS 2014 requirements, while the liquid limit and plasticity index are higher than the QCS 2014 permissible limits. Additionally, the morphological structure and the elemental composition of the raw TBM muck were determined by employing Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray analysis (EDX), respectively. Digital images were also taken at larger scale to draw a full picture of the TBM muck morphology. A mixture of rough-rounded to angular-elongated shaped particles with relatively large voids could be observed. The EDX analysis demonstrated the presence of silicon (Si) as the predominant component of the muck, which may alter the Coefficient of Thermal Expansion (CTE) values for mixtures prepared using TBM muck. Hence, further investigations should be performed on the mechanical and thermal properties of mixtures containing TBM muck as aggregates’ replacement, and further work should be directed toward this end.
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