A green palladium‐based catalyst supported on Artemisia abrotanum extract‐modified graphene oxide (Pd NPs/RGO‐A. abrotanum) hybrid material has been used as a recoverable and heterogeneous nanocatalyst for the catalytic reduction of various dyes, including methylene blue, methyl orange and rhodamine B, in the presence of NaBH4 as reducing agent in aqueous medium at room temperature. With the help of UV–visible spectroscopy, the catalytic reactions were investigated. According to the results, these reactions followed the pseudo‐first‐order rate equation.
In this paper, the preparation of a novel magnetic nanocatalyst (Fe3O4@PVA/CuCl) is described, which involves coating of polyvinyl alcohol (PVA) onto the surface of Fe3O4 nanoparticles and its subsequent coordination with CuCl catalyst. The nanocatalyst was characterized by various analytical methods, including Fourier‐transform infrared, X‐ray diffraction, inductively coupled plasma spectroscopy, field emission scanning electron microscopy, energy‐dispersive X‐ray spectroscopy (EDX), transmission electron microscopy, vibrating‐sample magnetometry, and EDX elemental mapping. Moreover, the nanocatalyst was efficiently used in the N‐arylation of amines via the formation of a carbon–nitrogen bond between the aryl halides and amines by Ullmann‐type coupling reactions. The catalyst was sufficiently stable and can be reused for at least seven times in a model Ullmann reaction without remarkable alteration in its catalytic behavior. Heterogeneity of the catalyst was investigated by a hot filtration test.
This paper develops a green method for in situ decorated of palladium nanoparticles over Fe 3 O 4 nanoparticles, by utilizing Strawberry fruit extract and ultrasound irradiations, with no use of any toxic reducing agent. The structure's characterization is represented via diverse analytical methods such as FT-IR, FE-SEM, TEM, WDX, ICP, EDS and XXPS. Catalytic efficiency of magnetic Fe 3 O 4 @Strawberry/Pd nanocatalyst is investigated in production of different biphenyls with good turnover frequencies (TOF) and turnover numbers (TON) through Suzuki coupling reactions. Furthermore, the catalyst could be recovered and reused 7 runs without considerable palladium leaching or alteration in its performance.
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