A vanadium–boron distance of 1.971 Å characterizes the first classical bond between these two elements. The novel half‐sandwich complex 1 was obtained from [(OC)5CrBN(SiMe3)2] by photochemically induced intermetallic borylene transfer.
Over the past seven years, complexes of various transition metals with bridged or terminal borylene ligands BR have for the first time been reported and fully characterised. Being closely related to important organometallic compounds, such as carbene, vinylidene, and carbonyl complexes, they have already attracted considerable interest both from experimental and computational points of view. Those studies have provided some detailed information about the nature of the
Ein Vanadium‐Bor‐Abstand von 1.971 Å charakterisiert die erste klassische Bindung zwischen diesen beiden Elementen. Der neuartige Halbsandwichkomplex 1 wurde ausgehend von [(OC)5CrBN(SiMe3)2] durch photochemisch induzierten Borylentransfer erhalten.
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