The presence of ophicalcites in serpentinized peridotites together with fragments of these rocks in Cretaceous breccias along several North-Pyrenean basins led to the interpretation of complete mantle exhumation to the seafloor. The westernmost outcrop of peridotites in the Pyrenean-Cantabrian belt is located in Ziga (eastern Basque-Cantabrian Basin), associated to a band of HT metamorphism related to the Leiza fault (Marble Unit). We present a petrological and geochemical study of the marbles and Ziga peridotite-hosted calcite, including standard stable isotope composition and clumped isotope geothermometry. These isotopic techniques allow the determination of different types of formational fluids and crystallization temperatures, and are a useful tool for studying carbonation processes in hyperextended basins. Fieldwork and analytical studies lead us to conclude that during the opening of the Bay of Biscay, mantle rocks were unroofed at the base of the sedimentary pile of the eastern Basque-Cantabrian Basin. However, the ophicalcite veins were recrystallized from meteoric fluids at low temperatures (498C). The primary carbonate phase may have been formed either during the mid-Cretaceous unroofing of the mantle or in a post-exhumation stage. The process of mantle exhumation was accompanied with HT-LP metamorphism and fluid circulation along major faults that reset the marine isotopic signature in the nearest marbles. For comparison, ophicalcites from Urdach and Lherz (North-Pyrenean Zone) were included in the clumped isotope study. Results show that they were recrystallized from hot (200-2308C), saline fluids, and from meteoric fluids at near ambient temperatures (32-428C), respectively.
Biodiversity hotspots and geosites are indivisible parts of natural heritage. Therefore, an adequate spatial delimitation and understanding of both and their linkages are necessary in order to be able to establish conservation policies. Normally, biodiversity hotspots are a typical target for those policies but, generally, geosites are not taken into account. Thus, this paper aims to fill this gap by providing an easily replicable method for the identification and integration of the geosites and the biodiversity hotspots in a Network for Integrative Nature Conservation that highlights their linkages. The method here presented has been applied to Urdaibai Biosphere Reserve situated in southeastern of the Bay of Biscay. The obtained results indicate that some geosites that are not directly related with biodiversity hotspots remain unprotected. Thus, from the study carried out, it can be stated that we conserving just the biodiversity hotspots is not enough to conserve the whole natural heritage of a protected area, as some plots interesting due to their relevant geoheritage remain unprotected. Therefore, it is necessary to fully integrate geosites into the planning documents of protected areas as a part of an ecosystem approach. The ecosystem approach recognizes the integrity of abiotic and biotic elements in nature conservation policies. Moreover, the proposed framework and the innovative methodology can be used as an easy input to identify priority areas for conservation, to improve the protected areas conservation planning, and to demonstrate the linkages between biodiversity hotspots and geosites.
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