The availability of a considerable amount of waste carbon fiber (CF) and the increased pressure to recycle/reuse materials at the end of their life cycle have put the utilization of recycled CF (rCF) under the spotlight. This article reports the successful manufacturing of hybrid yarns consisting of staple CF cut from virgin CF filament yarn and polyamide 6 fibers of defined lengths (40 and 60 mm). Carding and drawing are performed to prepare slivers with improved fiber orientation and mixing for the manufacturing of hybrid yarns. The slivers are then spun into hybrid yarns on a flyer machine. The investigations reveal the influence of fiber length and mixing ratio on the quality of the card web, slivers and on the strength of the hybrid yarns. The findings based on the results of this research work will help realize value-added products from rCF on an industrial scale in the near future.
This article reports the successful manufacturing of hybrid yarns from virgin staple CF (40 or 60 mm) or recycled staple CF (rCF) by mixing with polyamide 6 (PA 6) fibers of defined length. The hybrid yarns are produced using an optimized process route of carding, drawing, and flyer machine. Furthermore, the influence of CF length, CF type (i.e. virgin or rCF), CF volume content, and twist of the yarn are also investigated regarding the tensile properties of unidirectionally laid (UD) thermoplastic composites. The results show that CF length, yarn twist, and CF content of composites play a big role on the tensile properties of thermoplastic composites. From the comparison of tensile strength of UD composites produced from 40 and 60 mm virgin staple CF, it can be seen that the increase of yarn twist decreases the tensile strength. However, the effect of twist on the tensile properties of UD composites manufactured from 40 mm virgin staple CF is insignificant. The tensile strength of UD thermoplastic composites manufactured from the hybrid yarn with 40 and 60 mm virgin staple CF and rCF is found to be 771 ± 100, 838 ± 81, and 801 ± 53.4 MPa, respectively, in the case of 87 T/m containing 50 volume% CF.
The aim of this paper is to highlight recent developments in the processing of waste carbon fibre for thermoplastic composites. Initially, injection moulding and nonwoven technologies have been used to integrate waste carbon fibres into fibre-reinforced thermoplastic composites. Recently, tape and hybrid yarn spinning technologies have been developed to produce tape and hybrid yarn structures from waste carbon fibre, which are then used to manufacture recycled carbon fibre-reinforced thermoplastics with much higher efficiency. The hybrid yarn spinning technologies enable the development of various fibrous structures with higher fibre orientation, compactness and fibre volume fraction. Therefore, thermoplastic composites manufactured from hybrid yarns possess a good potential for use in load-bearing structural applications. In this paper, a comprehensive review on novel and existing technologies employed for the processing of waste carbon fibre in addition to different quality aspects of waste carbon fibre is presented.
The surface of silica nanoparticles has been modified using four sets of reagents: trimethoxysilanes (TMS), methoxysilanes (MS), dimethoxysilanes (DMS), and polydimethylsiloxanes (PDMS). Characterization of the organic loading and structure has been carried out. Glass slides have been coated with the organosilicas, and the wetting/topographic properties studied. Especially for the TMS organosilica series, the wetting behaviour of the coatings changes from very hydrophobic to superhydrophobic and finally to ''pearl'' bouncing droplets with contact angle of 180 , as the length of the silane alkyl side chain increases. The length of the side chain modifies not only the surface chemistry but also the aggregation state of the nanosilica, and thus controls the coating topography at the nano-, submicro and micrometre scales. This has been called ''chemically guided topography'', and it produces a hierarchical structure dependent on the silica surface coverage, leading to different wetting responses.
Experimental section
MaterialsSilica nanoparticles, Aerosil 200 (A200, Degussa), were used without any further drying. The trimethoxysilanes: methyl
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