It is generally understood that foxtail millet and broomcorn millet were initially domesticated in Northern China where they eventually became the dominant plant food crops. The rarity of older archaeological sites and archaeobotanical work in the region, however, renders both the origins of these plants and their processes of domestication poorly understood. Here we present ancient starch grain assemblages recovered from cultural deposits, including carbonized residues adhering to an early pottery sherd as well as grinding stone tools excavated from the sites of Nanzhuangtou (11.5-11.0 cal kyBP) and Donghulin (11.0-9.5 cal kyBP) in the North China Plain. Our data extend the record of millet use in China by nearly 1,000 y, and the record of foxtail millet in the region by at least two millennia. The patterning of starch residues within the samples allow for the formulation of the hypothesis that foxtail millets were cultivated for an extended period of two millennia, during which this crop plant appears to have been undergoing domestication. Future research in the region will help clarify the processes in place.starch grain analysis | agriculture origins | early Neolithic | millet domestication | East Asia

No abstract

Abstract:China is distinguished by a prominent monsoonal climate in the east of the country, a continental arid climate in the northwest and a highland cold climate on the Qinghai-Tibet Plateau. Because of the long history of Chinese civilization, there are abundant and well-dated documentary records for climate variation over the whole of the country as well as many natural archives (e.g., tree-rings, ice cores, stalagmites, varved lake sediments and corals) that enable high-resolution paleoclimatic reconstruction. In this paper, we review recent advances in the reconstruction of climate and extreme events over the last 2000 years in China. In the last 10 years, many new reconstructions, based on multi-proxies with wide spatial coverage, have been published in China. These reconstructions enable us to understand the characteristics of climate change across the country as well as the uncertainties of regional reconstructions. Synthesized reconstructed temperature results show that warm intervals over the last 2000 years occurred in AD 1-200, AD 551-760, AD 951-1320, and after AD 1921, and also show that cold intervals were in AD 201-350, AD 441-530, AD 781-950, and AD 1321-1920. Extreme cold winters, seen between 1500 and 1900, were more frequent than those after 1950. The intensity of regional heat waves, in the context of recent global warming, may not in fact exceed natural climate variability seen over the last 2000 years. In the eastern monsoonal region of China, decadal, multi-decadal and centennial oscillations are seen in rainfall variability. While the ensemble mean for drought/flood spatial patterns across all cold periods shows a meridional distribution, there is a tri-pole pattern with respect to droughts south of 25°N, floods between 25° and 30°N, and droughts north of 30°N for all warm periods. Data show that extreme drought events were most frequent in the periods AD

Directed self-assembly (DSA) of block copolymers (BCPs) is an attractive advanced patterning technology being considered for future integrated circuit manufacturing. By controlling interfacial interactions, self-assembled microdomains in thin films of polystyrene-block-poly(methyl methacrylate), PS-b-PMMA, can be oriented perpendicular to surfaces to form line/space or hole patterns. However, its relatively weak Flory interaction parameter, χ, limits its capability to pattern sub-10 nm features. Many BCPs with higher interaction parameters are capable of forming smaller features, but these "high-χ" BCPs typically have an imbalance in surface energy between the respective blocks that make it difficult to achieve the required perpendicular orientation. To address this challenge, we devised a polymeric surface active additive mixed into the BCP solution, referred to as an embedded neutral layer (ENL), which segregates to the top of the BCP film during casting and annealing and balances the surface tensions at the top of the thin film. The additive comprises a second BCP with a "neutral block" designed to provide matched surface tensions with the respective polymers of the main BCP and a "surface anchoring block" with very low surface energy that drives the material to the air interface during spin-casting and annealing. The surface anchoring block allows the film to be annealed above the glass transition temperature of the two materials without intermixing of the two components. DSA was also demonstrated with this embedded neutral top layer formulation on a chemical patterned template using a single step coat and simple thermal annealing. This ENL technology holds promise to enable the use of high-χ BCPs in advanced patterning applications.

Poor preservation of plant macroremains in the acid soils of southern subtropical China has hampered understanding of prehistoric diets in the region and of the spread of domesticated rice southwards from the Yangtze River region. According to records in ancient books and archaeological discoveries from historical sites, it is presumed that roots and tubers were the staple plant foods in this region before rice agriculture was widely practiced. But no direct evidences provided to test the hypothesis. Here we present evidence from starch and phytolith analyses of samples obtained during systematic excavations at the site of Xincun on the southern coast of China, demonstrating that during 3,350–2,470 aBC humans exploited sago palms, bananas, freshwater roots and tubers, fern roots, acorns, Job's-tears as well as wild rice. A dominance of starches and phytoliths from palms suggest that the sago-type palms were an important plant food prior to the rice in south subtropical China. We also believe that because of their reliance on a wide range of starch-rich plant foods, the transition towards labour intensive rice agriculture was a slow process.

A modular approach has been developed for the synthesis of rod–coil block copolymers involving the initial preparation of a macroinitiator based on the rod block followed by the growth of the coil segment with living free‐radical procedures. The key feature of this strategy is the utilization of an alkoxyamine group from the beginning of the synthesis, which serves as a solubilizing group and ensures that each rod block contains a single initiating fragment. Using this approach permits block copolymers based on insoluble biphenyl ester oligomers to be conveniently prepared with coil segments that range from styrenes to acrylates to 1,3‐dienes. The tendency of the rod segments to crystallize is strongly dependent on the weight fraction of the rod segment and the chemical nature of the coil segment. Rod–coil molecules containing at least 25–35 wt % polystyrene or poly(n‐butyl acrylate) coil segments show a two‐dimensional hexagonal arrangement of rod aggregates, as characterized by transmission electron microscopy and small‐angle X‐ray scattering. Polyisoprene block copolymers exhibit a lamellar microstructure with short rigid domains in which the rod units lie in an interdigitated smectic C arrangement. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3640–3656, 2003

No abstract

No abstract