A green bioreductive approach with Cacumen Platycladi (CP) extract was adopted to fabricate bimetallic Au− Pd/TiO 2 catalysts for solvent-free oxidation of benzyl alcohol (BzOH) to benzaldehyde (BzH) with molar oxygen at atmospheric pressure. The Au−Pd nanoparticles (NPs) before being immobilized onto TiO 2 were determined by transmission electron microscopy. And, the catalysts were further analyzed by X-ray diffraction, X-ray photoelectron spectroscopy, thermogravimetric analysis, etc. Effects of Au/Pd molar ratio, preparation conditions, and reaction conditions on the catalytic activity of Au− Pd/TiO 2 were investigated. And, the Au−Pd/TiO 2 catalyst without calcination that was prepared at 90 °C from the Au−Pd NPs with Au/Pd molar ratio of 2:1 exhibited excellent catalytic performance. With the catalyst, BzOH conversion of 74.2% and selectivity to BzH 95.8% were attained at the reaction temperature of 90 °C with an oxygen flow rate of 90 mL/min. Meanwhile, the recycling tests showed that, after seven recycles, the catalyst still remained with high conversion and selectivity. Therefore, the catalyst had excellent durability and reusability and good prospects for industrial application.
Self‐assembly guided by biological molecules is a promising approach for fabricating predesigned nanostructures. Protein is one such biomolecule possessing deterministic 3D crystal structure and peptide information, which acts as a good candidate for templating functional nanoparticles (fNPs). However, inadequate coordination efficacy during the establishment of interfacial interactions with fNPs makes it highly challenging to precisely fabricate designed nanostructures and functional materials. Here, a facile and robust strategy is reported for the hierarchical assembly of fNPs into ordered architectures, with unprecedentedly large sizes up to tens of micrometers, using a hollow cylinder‐shaped tobacco mosaic virus coat protein (TMV disk). The rational design of the site‐specific functional groups on the TMV disk not only demonstrates the powerful capability of directing various discrete fNP assemblies with high controllability but also assists in precise assembly of a TMV monolayer sheet structure for further organizing homogeneous and heterogeneous fNP periodic lattices by varying the types of fNPs. The high precision and adjustability of the pattern fashions of different fNPs unambiguously corroborate the validity of this innovative strategy, which provides a convenient route to design and assemble protein‐based hierarchical ordered architectures for use in nanophotonics and nanodevices.
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