Stress exists ubiquitously and is critically important for the manufacturing industry. Due to the ultrasensitive mechanoresponse of the emission of 1,1,2,2,-tetrakis(4-nitrophenyl)ethane (TPE-4N), a luminogen with aggregation-induced emission characteristics, the visualization of stress/strain distributions on metal specimens with a pure organic fluorescent material is achieved. Such a fluorescence mapping method enjoys the merits of simple setup, real-time, full-field, on-site, and direct visualization. Surface analysis shows that TPE-4N can form a nonfluorescent, crystalline uniform film on the metal surface, which cracks into fluorescent amorphous fragments upon mechanical force. Therefore, the invisible information of the stress/strain distribution of the metal specimens are transformed to visible fluorescent signals, which generally matches well but provides more details than software simulation. Remarkably, fatigue crack propagation in stainless steel and aluminum alloy can be observed and predicted clearly, further demonstrating the ultrasensitivity and practicability of TPE-4N.

Local strain concentration is critically important for damage formation of structural components. Therefore, it is of particular interest in developing the structural health monitoring (SHM) method for large-scale, full-field, and on-site monitoring of local strain response in complicated structural components in service. The present work investigated a SHM method based on a pure organic mechanoresponsive luminogen (MRL), 1,1,2,2-tetrakis­(4-nitrophenyl)­ethane, for heterogeneous local strain concentration. Invisible heterogeneous local strain response in complicated weld joints is transformed into visible fluorescence under monotonic tension and cyclic stress loading. The local strain (<15%) calculated by fluorescence intensity has a good agreement with the results obtained by the conventional digital image correlation method, indicating good measurement accuracy of the calibrated organic MRL method. The heterogeneity of local strain in complicated weld joints increases along with elongation and number of stress cycles. Moreover, the higher mean stress and stress amplitude can induce significantly higher accumulated local strain in the relatively soft fusion zone region. Compared with conventional strain measurement methods, the present organic MRL method opens up new possibilities for large-scale, full-field, and on-site monitoring of local strain concentration and damage in complicated structural components.

Stress is critically important for the manufacturing industry. The visualization of stress/strain distributions and fatigue crack propagation on metal specimens with a pure organic fluorescent material is achieved by Zhe Zhang, Ben Zhong Tang, and co‐workers in article number https://doi.org/10.1002/adma.201803924. Such a method enjoys the merits of a simple setup and real‐time, full‐field, on‐site, and direct visualization. The invisible information of the mechanical response of the metal specimens are transformed to visible fluorescent signals.