Two novel aromatic imides, diarylcyclopentadienone-fused naphthalimides (BCPONI-2Br and TCPONI-2Br), are designed and synthesized by condensation coupling cyclopentadienone derivatives at the lateral position of naphthalimide skeleton. It has been found that BCPONI-2Br and TCPONI-2Br are highly electron-withdrawing acceptor moieties, which possess broad absorption bands and very low-lying LUMO energy levels, as low as −4.02 eV. On the basis of both building blocks, six low bandgap D-A copolymers (P1–P6) are prepared via Suzuki or Stille coupling reactions. The optical and electrochemical properties of the polymers are fine-tuned by the variations of donors (carbazole, benzodithiophene, and dithienopyrrole) and π-conjugation linkers (thiophene and benzene). All polymers exhibit several attractive photophysical and electrochemical properties, i.e., broad near-infrared (NIR) absorption, deep-lying LUMO levels (between −3.88 and −3.76 eV), and a very small optical bandgap as low as 0.81 eV, which represents the first aromatic diimide-based polymer with an of <1.0 eV. An investigation of charge carrier transport properties shows that P5 exhibits a moderately high hole mobility of 0.02 cm 2 V −1 s −1 in bottom-gate field-effect transistors (FETs) and a typical ambipolar transport behavior in top-gate FETs. The findings suggest that BCPONI-2Br, TCPONI-2Br, and the other similar acceptor units are promising building blocks for novel organic semiconductors with outstanding NIR activity, high electron affinity, and low bandgap, which can be extended to various next-generation optoelectronic devices.
Valley photonic crystals (VPCs) have provided a novel topological photonic platform to manipulate light. In this work, we construct zigzag and armchair domain walls using two-dimensional silicon VPCs, the edges between domains of opposite valley indices link to the corresponding topological invariant. We study the light transmission of these edges with defects and sharp bent corners. We design all-optical logic gates at telecommunication wavelength with both XOR and OR functions based on the valley-contrasting edges. Topologically protected waveguides own high transmission and backscattering-immune features, and the coupling process of different edge modes results in interference for logic functions. Compared with traditional photonic crystal logic gates, our device shows outstanding properties, including robust transmission, higher contrast ratio and more compact footprint. Furthermore, our work also shows the potential of topological photonics to be applied in optical logic circuits.
This paper presents an all-dielectric chiral metasurface composed of an array of two-layer distorted square structures with nanoholes. This metasurface can simultaneously generate dual-band opposite chiral responses, which can be attributed to the bound states in the continuum (BICs) and the distorted chiral structure. By combining the BICs with chirality, a dual-band chiral nonlinear metasurface and a chiral-sensing method are proposed. The simulated results show that the third harmonic generation (THG) conversion efficiency can reach the order of 10 −4 for two peaks with a peak-pump intensity of approximately 5.3 GW cm −2 in the near-infrared region. Moreover, the third-harmonic circular dichroism for each peak can reach up to 0.99 and -0.94, respectively. Furthermore, it is theoretically demonstrated that this metasurface can be used for chiral sensing with high sensitivities. These results provide new insights for linear and nonlinear spin-dependent applications.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.