Polymer supported vanadium complexes (denoted as c-PMA n -V) were prepared by the complexation of vanadium ions onto a cross linked polyacrylate. cPMA n -V can catalyze the oxidative cleavage of olefins with a large excess of t-butyl hydroperoxide (TBHP) or bishydroxylation of olefins with 4 eq. of TBHP.
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