The development of well-organized structures with high luminescent properties in the solid and aggregated states is of both scientific and technological interest due to their applications in nanotechnology. In this paper we described the synthesis of amphiphilic and dumbbell shaped AIE-active tetraphenylethylene (TPE) derivatives and studied their self-assembly with solvophobic control. Interestingly, both TPE derivatives form a 3D flower-shape supramolecular structure from THF/water solutions at varying water fractions. SEM microscopy was used to visualise step-wise growth of flower-shape assembly. TPE derivatives also show good mechanochromic properties which can be observed in the process of grinding, fuming and heating. These TPE derivative self-assemblies are formed due to two main important properties: (i) the TPE-core along with alkyl chains, optimizing the dispersive interactions within a construct, and (ii) amide-linkage through molecular recognition. We believe such arrangements prevent crystallization and favour the directional growth of flower-shape nanostructures in a 3D fashion.

In this study, we report a facile synthetic protocol for the fabrication of well‐dispered porphyrin nanorods on the surface of graphene nanoplates (GNPs) by surfactant‐assisted self assembly of tetrakis (4‐carboxyphenyl) porphyrin (TCPP). The formation and crystalisation of GNPs‐supported TCPP nanorods were successfully characterized by SEM, XRD, FTIR, UV‐vis and fluorescence spectroscopy. The assembled TCPP nanorods with a 50 nm diameter and ∼250 nm in length are well distributed on the GNPs and was confirmed by electron microscopy i.e SEM and TEM. The resulted hybrid material shows enhanced visible‐light photocatalytic activity compared to free standing TCPP nanorods toward the degradation of Rhodamine B (RhB). In addition, the photodegradation mechanism of RhB when using GNPs‐supported TCPP nanorods catalyst is also proposed.

Abstract:The Tetraphenylethylene (TPE) based dumbbell shaped molecules TPE-Pi, TPE-Su, TPE-Az, and TPE-Se were synthesised bearing odd-even alkyl chains containing 7, 8, 9 and 10 carbons respectively. These molecules reveal typical Aggregation Induced Emission (AIE) behaviour. The influence of the odd or even alkyl chain length was shown by studying the morphology of self-assembled nanostructures formed in a range of tetrahydrofuran (THF)/water solvent systems. For example, with a water fraction of 80%, TPE derivatives with odd alkyl chains (TPE-Pi and TPE-Az) self-assembled into nanosphere structures, while TPE-Su with 8 alkyl chains formed microbelts and TPE-Se with 10 alkyl chains aggregated into flower-like superstructures. These TPE derivatives also revealed interesting mechanochromic properties upon grinding, fuming and heating, which reveal the importance of molecular stacking in the crystal structure to the luminescent properties of the aggregates .The mechanochromic properties of TPE-Pi, TPE-Su, and TPE-Az were also demonstrated by the process of grounding, fuming, and heating.

This review details the biological activity, biosynthesis and synthesis of isochromanone metabolites isolated from myxobacteria. Strategies towards the synthesis of the isochomanone and oxazole fragments of these natural products are...