The solubilities and diffusion coefficients of hydrogen sulfide and carbon dioxide gases in the ionic liquid (IL) 1-(2-hydroxyethyl)-3-methylimidazolium tetrafluoroborate ([hemim][BF 4 ]), at temperatures ranging from (303.15 to 353.15) K and pressures up to 1.1 MPa, were determined. The solubility data were correlated using the Krichevsky-Kasarnovsky equation, and Henry's law constants at different temperatures were obtained. From the solubility data, the partial molar thermodynamic functions of solution such as Gibbs energy, enthalpy, and entropy were calculated. The diffusion coefficients were obtained for H 2 S and CO 2 using a semi-infinite volume approach, and a correlation equation with temperature is presented for each gas. A comparison showed that the solubility of H 2 S was about three times its magnitude, and its diffusion coefficient is of the same order of magnitude as that of CO 2 in the IL studied in this work.
In this work SBA-15, a melamine-based functionalized SBA-15 mesoporous silica with a dicationic ionic liquid was used in order to improve the physicochemical properties of phosphoric acid doped polybenzimidazole membranes for application in HT-PEMFCs.
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